tert-butyl[(1Z,3Z)-4-(4-chlorophenyl)-1-phenylbuta-1,3-dien-1-yloxy]dimethylsilane

Base Information

Chemical Name:tert-butyl[(1Z,3Z)-4-(4-chlorophenyl)-1-phenylbuta-1,3-dien-1-yloxy]dimethylsilane
CAS No.:1402934-56-8
Molecular Formula:C₂₂H₂₇ClOSi
Molecular Weight:370.994
Hs Code.:

Synonyms:tert-butyl[(1Z,3Z)-4-(4-chlorophenyl)-1-phenylbuta-1,3-dien-1-yloxy]dimethylsilane

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Chemical Property of tert-butyl[(1Z,3Z)-4-(4-chlorophenyl)-1-phenylbuta-1,3-dien-1-yloxy]dimethylsilane

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Technology Process of tert-butyl[(1Z,3Z)-4-(4-chlorophenyl)-1-phenylbuta-1,3-dien-1-yloxy]dimethylsilane

There total 5 articles about tert-butyl[(1Z,3Z)-4-(4-chlorophenyl)-1-phenylbuta-1,3-dien-1-yloxy]dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1402934-41-1
3-(tert-butyldimethylsilanyl)-1-phenylpropen-1-one

: 104-88-1
4-chlorobenzaldehyde

: 1402934-55-7
tert-butyl[(1Z,3E)-4-(4-chlorophenyl)-1-phenylbuta-1,3-dien-1-yloxy]dimethylsilane

: 1402934-56-8
tert-butyl[(1Z,3Z)-4-(4-chlorophenyl)-1-phenylbuta-1,3-dien-1-yloxy]dimethylsilane

Guidance literature:: With tributylphosphine; In chloroform; at -20 ℃; for 1h; Overall yield = 92 %; stereoselective reaction; Inert atmosphere;
DOI:10.1016/j.tetlet.2012.08.114

Reference yield:

: 3-(tert-butyldimethylsilanyl)-1-phenylprop-2-en-1-ol

: 1402934-56-8
tert-butyl[(1Z,3Z)-4-(4-chlorophenyl)-1-phenylbuta-1,3-dien-1-yloxy]dimethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1: dipyridinium dichromate / dichloromethane / 2.5 h / 20 °C / Inert atmosphere; Molecular sieve

2: tributylphosphine / chloroform / 1 h / -20 °C / Inert atmosphere

With dipyridinium dichromate; tributylphosphine; In dichloromethane; chloroform;
DOI:10.1016/j.tetlet.2012.08.114

Reference yield:

: 887588-95-6
3-(tert-butyldimethylsilanyl)-1-phenylprop-2-yn-1-ol

: 1402934-56-8
tert-butyl[(1Z,3Z)-4-(4-chlorophenyl)-1-phenylbuta-1,3-dien-1-yloxy]dimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1: lithium aluminium tetrahydride / tetrahydrofuran / 4 h / 20 °C / Inert atmosphere

2: dipyridinium dichromate / dichloromethane / 2.5 h / 20 °C / Inert atmosphere; Molecular sieve

3: tributylphosphine / chloroform / 1 h / -20 °C / Inert atmosphere

With lithium aluminium tetrahydride; dipyridinium dichromate; tributylphosphine; In tetrahydrofuran; dichloromethane; chloroform;
DOI:10.1016/j.tetlet.2012.08.114