Trifluoro-methanesulfonate9-benzyl-2-trimethylsilanyl-4,9-dihydro-3H-β-carbolin-2-ium;

Base Information

Chemical Name:Trifluoro-methanesulfonate9-benzyl-2-trimethylsilanyl-4,9-dihydro-3H-β-carbolin-2-ium;
CAS No.:109355-90-0
Molecular Formula:CF₃O₃S*C₂₁H₂₅N₂Si
Molecular Weight:482.599
Hs Code.:

Synonyms:Trifluoro-methanesulfonate9-benzyl-2-trimethylsilanyl-4,9-dihydro-3H-β-carbolin-2-ium;

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Chemical Property of Trifluoro-methanesulfonate9-benzyl-2-trimethylsilanyl-4,9-dihydro-3H-β-carbolin-2-ium;

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Technology Process of Trifluoro-methanesulfonate9-benzyl-2-trimethylsilanyl-4,9-dihydro-3H-β-carbolin-2-ium;

There total 6 articles about Trifluoro-methanesulfonate9-benzyl-2-trimethylsilanyl-4,9-dihydro-3H-β-carbolin-2-ium; which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 771-51-7
indole-3-acetonitrile

: 109355-90-0
Trifluoro-methanesulfonate9-benzyl-2-trimethylsilanyl-4,9-dihydro-3H-β-carbolin-2-ium;

Guidance literature:: Multi-step reaction with 5 steps

1: 78 percent / NaH / benzene / 1.) reflux, 20 min; 2.) 12 h, room temp.

2: 95 percent / H₂, / 5percent Rh-Al₂O₃ / tetrahydrofuran; various solvent(s) / 48 h / 2068.6 Torr

3: 96 percent / 2 h / 120 °C

4: 77 percent / POCl₃ / ice bath, room temp. 10-20 min, 40 deg C, 5 min, room temp., 2 h

5: tetrahydrofuran / 1 h / -78 °C

With hydrogen; sodium hydride; trichlorophosphate; rhodium on alumina; In tetrahydrofuran; benzene;
DOI:10.1016/S0040-4020(01)87781-4

Reference yield:

: 100-44-7
benzyl chloride

: 109355-90-0
Trifluoro-methanesulfonate9-benzyl-2-trimethylsilanyl-4,9-dihydro-3H-β-carbolin-2-ium;

Guidance literature:: Multi-step reaction with 5 steps

1: 78 percent / NaH / benzene / 1.) reflux, 20 min; 2.) 12 h, room temp.

2: 95 percent / H₂, / 5percent Rh-Al₂O₃ / tetrahydrofuran; various solvent(s) / 48 h / 2068.6 Torr

3: 96 percent / 2 h / 120 °C

4: 77 percent / POCl₃ / ice bath, room temp. 10-20 min, 40 deg C, 5 min, room temp., 2 h

5: tetrahydrofuran / 1 h / -78 °C

With hydrogen; sodium hydride; trichlorophosphate; rhodium on alumina; In tetrahydrofuran; benzene;
DOI:10.1016/S0040-4020(01)87781-4

Reference yield:

: 59414-85-6
2-(1-benzyl-1H-indol-3-yl)acetonitrile

: 109355-90-0
Trifluoro-methanesulfonate9-benzyl-2-trimethylsilanyl-4,9-dihydro-3H-β-carbolin-2-ium;

Guidance literature:: Multi-step reaction with 4 steps

1: 95 percent / H₂, / 5percent Rh-Al₂O₃ / tetrahydrofuran; various solvent(s) / 48 h / 2068.6 Torr

2: 96 percent / 2 h / 120 °C

3: 77 percent / POCl₃ / ice bath, room temp. 10-20 min, 40 deg C, 5 min, room temp., 2 h

4: tetrahydrofuran / 1 h / -78 °C

With hydrogen; trichlorophosphate; rhodium on alumina; In tetrahydrofuran;
DOI:10.1016/S0040-4020(01)87781-4