3-Chloro-2-((E)-2-oxo-octa-3,7-dienyl)-4,6-bis-(2-trimethylsilanyl-ethoxymethoxy)-benzoic acid (R)-1-methyl-but-3-enyl ester

Base Information

Chemical Name:3-Chloro-2-((E)-2-oxo-octa-3,7-dienyl)-4,6-bis-(2-trimethylsilanyl-ethoxymethoxy)-benzoic acid (R)-1-methyl-but-3-enyl ester
CAS No.:873208-00-5
Molecular Formula:C₃₂H₅₁ClO₇Si₂
Molecular Weight:639.377
Hs Code.:

Synonyms:3-Chloro-2-((E)-2-oxo-octa-3,7-dienyl)-4,6-bis-(2-trimethylsilanyl-ethoxymethoxy)-benzoic acid (R)-1-methyl-but-3-enyl ester

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Chemical Property of 3-Chloro-2-((E)-2-oxo-octa-3,7-dienyl)-4,6-bis-(2-trimethylsilanyl-ethoxymethoxy)-benzoic acid (R)-1-methyl-but-3-enyl ester

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Technology Process of 3-Chloro-2-((E)-2-oxo-octa-3,7-dienyl)-4,6-bis-(2-trimethylsilanyl-ethoxymethoxy)-benzoic acid (R)-1-methyl-but-3-enyl ester

There total 4 articles about 3-Chloro-2-((E)-2-oxo-octa-3,7-dienyl)-4,6-bis-(2-trimethylsilanyl-ethoxymethoxy)-benzoic acid (R)-1-methyl-but-3-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 853645-31-5
hepta-2,6-dienoic acid methoxy-methylamide

: 873207-99-9
3-Chloro-2-methyl-4,6-bis-(2-trimethylsilanyl-ethoxymethoxy)-benzoic acid (R)-1-methyl-but-3-enyl ester

: 873208-00-5
3-Chloro-2-((E)-2-oxo-octa-3,7-dienyl)-4,6-bis-(2-trimethylsilanyl-ethoxymethoxy)-benzoic acid (R)-1-methyl-but-3-enyl ester

Guidance literature:: 3-Chloro-2-methyl-4,6-bis-(2-trimethylsilanyl-ethoxymethoxy)-benzoic acid (R)-1-methyl-but-3-enyl ester; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃;

hepta-2,6-dienoic acid methoxy-methylamide; In tetrahydrofuran; at -78 ℃; for 0.166667h;
DOI:10.1021/ol052263+

Reference yield:

: 853645-35-9
3-chloro-4,6-dihydroxy-2-methylbenzoic acid 1-methylbut-3-enyl ester

: 873208-00-5
3-Chloro-2-((E)-2-oxo-octa-3,7-dienyl)-4,6-bis-(2-trimethylsilanyl-ethoxymethoxy)-benzoic acid (R)-1-methyl-but-3-enyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: 944 mg / NaH / tetrahydrofuran / 2 h / 0 °C

2.1: LDA / tetrahydrofuran / -78 °C

2.2: 60 percent / tetrahydrofuran / 0.17 h / -78 °C

With sodium hydride; lithium diisopropyl amide; In tetrahydrofuran;
DOI:10.1021/ol052263+

Reference yield:

: 625-31-0,64584-92-5,111957-98-3,55563-79-6
(S)-4-penten-2-ol

: 873208-00-5
3-Chloro-2-((E)-2-oxo-octa-3,7-dienyl)-4,6-bis-(2-trimethylsilanyl-ethoxymethoxy)-benzoic acid (R)-1-methyl-but-3-enyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: tris-(3-chlorophenyl)phosphine; polystyrene-supported DEAD / toluene / 0.17 h / 20 °C

2.1: 944 mg / NaH / tetrahydrofuran / 2 h / 0 °C

3.1: LDA / tetrahydrofuran / -78 °C

3.2: 60 percent / tetrahydrofuran / 0.17 h / -78 °C

With polystyrene-supported DEAD; tri(m-chlorophenyl)-phosphine; sodium hydride; lithium diisopropyl amide; In tetrahydrofuran; toluene;
DOI:10.1021/ol052263+