hexacarbonylniobate(-I)

Base Information

Chemical Name:hexacarbonylniobate(-I)
CAS No.:45046-84-2
Molecular Formula:C₆NbO₆
Molecular Weight:260.969
Hs Code.:

Synonyms:hexacarbonylniobate(-I)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of hexacarbonylniobate(-I)

Chemical Property:

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Technology Process of hexacarbonylniobate(-I)

There total 2 articles about hexacarbonylniobate(-I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 15602-39-8
sodium{(THF)2.3} hexacarbonylniobate

: 948-43-6
N-methylacridinium iodide

: {octacarbonyl(niobium)2(μ-I)3}(1-)

: 45046-84-2
hexacarbonylniobate(-I)

: 3295-69-0
10,10'-dimethyl-9,10,9',10'-tetrahydro-[9,9']biacridinyl

Guidance literature:: In water; byproducts: CO; React. of starting materials in H2O under N2 or Ar atmosphere.; Evolution of CO obsd. (gas chromy.). Filtn. of pptd. colorless solid, washing with H2O and drying (vac.) over P4O10 gives org. compd. Extn. of aq. soln. (Et2O), evapn. of combined ether ext. to dryness under reduced pressure, IR spectoscopy.;
DOI:10.1021/om00095a011

Reference yield:

: 34134-62-8
{(C₂H₅)4N}⁽¹⁺⁾*{Nb(CO)4(C₆H₅)2PCH₂CH₂P(C₆H₅)2}^(1-)={N(C₂H₅)4}{Nb(CO)4(C₆H₅)2PCH₂CH₂P(C₆H₅)2}

: 45046-84-2
hexacarbonylniobate(-I)

: 93800-25-0
HNb(CO)4((C₆H₅)2P(CH₂)2P(C₆H₅)2)

Guidance literature:: With silica gel; In tetrahydrofuran; acetonitrile; (N2); complex soln. transferred to silica gel column, eluated with THF; pptd. with pentane;
DOI:10.1016/0022-328X(84)80629-4

Reference yield: 1.0%

: 45046-84-2
hexacarbonylniobate(-I)

: 15912-80-8,763019-84-7
Tetraphenylarsonium

: 603-35-0
triphenylphosphine

: 29609-45-8
(C₆H₅)4As⁽¹⁺⁾*Nb(CO)5P(C₆H₅)3^(1-)={(C₆H₅)4As}{Nb(CO)5P(C₆H₅)3}

Guidance literature:: With sodium; In hydrogenchloride; benzene; stirring of soln., exclusion of air, then addition of Na-amalgam (1% Na), reaction of Na-salt with tetraphenyl arsonium salt;;
DOI:10.1016/S0022-328X(00)92779-7