tert-butyl 3-(carbobenzyloxyamino)-4-C-carbomethoxy-2,3,4,6-tetradeoxy-2-C-methyl-α-D-glucopyranoside

Base Information

Chemical Name:tert-butyl 3-(carbobenzyloxyamino)-4-C-carbomethoxy-2,3,4,6-tetradeoxy-2-C-methyl-α-D-glucopyranoside
CAS No.:114059-54-0
Molecular Formula:C₂₁H₃₁NO₆
Molecular Weight:393.48
Hs Code.:

Synonyms:tert-butyl 3-(carbobenzyloxyamino)-4-C-carbomethoxy-2,3,4,6-tetradeoxy-2-C-methyl-α-D-glucopyranoside

Suppliers and Price of tert-butyl 3-(carbobenzyloxyamino)-4-C-carbomethoxy-2,3,4,6-tetradeoxy-2-C-methyl-α-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of tert-butyl 3-(carbobenzyloxyamino)-4-C-carbomethoxy-2,3,4,6-tetradeoxy-2-C-methyl-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of tert-butyl 3-(carbobenzyloxyamino)-4-C-carbomethoxy-2,3,4,6-tetradeoxy-2-C-methyl-α-D-glucopyranoside

There total 26 articles about tert-butyl 3-(carbobenzyloxyamino)-4-C-carbomethoxy-2,3,4,6-tetradeoxy-2-C-methyl-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 119794-80-8
tert-butyl 3-(carbobenzyloxyamino)-4-C-carbomethoxy-2,3,4,6-tetradeoxy-6-iodo-2-C-methyl-α-D-glucopyranoside

: 114059-54-0
tert-butyl 3-(carbobenzyloxyamino)-4-C-carbomethoxy-2,3,4,6-tetradeoxy-2-C-methyl-α-D-glucopyranoside

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; for 0.166667h; Heating;
DOI:10.1021/jo00270a019

Reference yield: 92.0%

: (2S,3S,4R,5R,6R)-4-Benzyloxycarbonylamino-2-bromomethyl-6-tert-butoxy-5-methyl-tetrahydro-pyran-3-carboxylic acid methyl ester

: 114059-54-0
tert-butyl 3-(carbobenzyloxyamino)-4-C-carbomethoxy-2,3,4,6-tetradeoxy-2-C-methyl-α-D-glucopyranoside

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; Heating;
DOI:10.1021/jo00244a061

Reference yield:

: 119794-57-9
tert-butyl 6-O-(tert-butyldimethylsilyl)-3,4-dideoxy-α-D-glycero-hex-3-enopyranosid-2-ulose

: 114059-54-0
tert-butyl 3-(carbobenzyloxyamino)-4-C-carbomethoxy-2,3,4,6-tetradeoxy-2-C-methyl-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 11 steps

1: Irradiation

2: pyridine / CH₂Cl₂

3: 94 percent / t-BuOH / tetrahydrofuran / 1.) from -78 deg C to 0 deg C, 2.) -78 deg C

4: 94 percent / diethyl ether

5: 86 percent / SOCl₂, pyridine

6: H₂ / Raney Ni / methanol

7: methanol

8: 84 percent / DIBAL / CH₂Cl₂ / -78 °C

9: 81 percent / n-Bu₄NF / tetrahydrofuran

10: 88 percent / 1.) Ph₃P, I₂, imidazole / tetrahydrofuran; benzene

11: 92 percent / Bu₃SnH, AIBN / benzene / Heating

With pyridine; 1H-imidazole; thionyl chloride; 2,2'-azobis(isobutyronitrile); tetrabutyl ammonium fluoride; hydrogen; iodine; tri-n-butyl-tin hydride; diisobutylaluminium hydride; triphenylphosphine; tert-butyl alcohol; nickel; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; benzene;
DOI:10.1021/jo00244a061