4-<<3-O-methyl-2,4-bis-O-(triethylsilyl)-α-L-rhamnopyranosyl>oxy>-5-iodo-2,3-dimethoxy-6-methylbenzaldehyde

Base Information

Chemical Name:4-<<3-O-methyl-2,4-bis-O-(triethylsilyl)-α-L-rhamnopyranosyl>oxy>-5-iodo-2,3-dimethoxy-6-methylbenzaldehyde
CAS No.:150650-46-7
Molecular Formula:C₂₉H₅₁IO₈Si₂
Molecular Weight:710.795
Hs Code.:

Synonyms:4-<<3-O-methyl-2,4-bis-O-(triethylsilyl)-α-L-rhamnopyranosyl>oxy>-5-iodo-2,3-dimethoxy-6-methylbenzaldehyde

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Chemical Property of 4-<<3-O-methyl-2,4-bis-O-(triethylsilyl)-α-L-rhamnopyranosyl>oxy>-5-iodo-2,3-dimethoxy-6-methylbenzaldehyde

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Technology Process of 4-<<3-O-methyl-2,4-bis-O-(triethylsilyl)-α-L-rhamnopyranosyl>oxy>-5-iodo-2,3-dimethoxy-6-methylbenzaldehyde

There total 26 articles about 4-<<3-O-methyl-2,4-bis-O-(triethylsilyl)-α-L-rhamnopyranosyl>oxy>-5-iodo-2,3-dimethoxy-6-methylbenzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 168567-22-4
4-<(6-deoxy-3-O-methyl-2,4-O,O-bis(triethylsilyl)-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylbenzonitrile

: 150650-46-7
4-<<3-O-methyl-2,4-bis-O-(triethylsilyl)-α-L-rhamnopyranosyl>oxy>-5-iodo-2,3-dimethoxy-6-methylbenzaldehyde

Guidance literature:: With diisobutylaluminium hydride; In hexane; toluene; at 0 ℃;
DOI:10.1021/ja00126a013

Reference yield: 80.0%

: 131675-59-7
4-<<3-O-methyl-2,4-bis-O-(triethylsilyl)-α-L-rhamnopyranosyl>oxy>-5-iodo-2,3-dimethoxy-6-methylbenzyl alcohol

: 150650-46-7
4-<<3-O-methyl-2,4-bis-O-(triethylsilyl)-α-L-rhamnopyranosyl>oxy>-5-iodo-2,3-dimethoxy-6-methylbenzaldehyde

Guidance literature:: With dipyridinium dichromate; In dichloromethane; for 1.5h;

Reference yield:

: 79271-56-0
triethylsilyl trifluoromethyl sulfonate

: 150650-46-7
4-<<3-O-methyl-2,4-bis-O-(triethylsilyl)-α-L-rhamnopyranosyl>oxy>-5-iodo-2,3-dimethoxy-6-methylbenzaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / pyridine, DMAP / CH₂Cl₂ / 14 h / Ambient temperature

2: 84 percent / i-Bu₂AlH / toluene; hexane / 0 °C

With pyridine; dmap; diisobutylaluminium hydride; In hexane; dichloromethane; toluene;
DOI:10.1021/ja00126a013