[(C₅H₅)(CO)(P(C₆H₅)3)Fe(C(SCH₃)2)]⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)(CO)(P(C₆H₅)3)Fe(C(SCH₃)2)]PF₆

Base Information

• Chemical Name: [(C₅H₅)(CO)(P(C₆H₅)3)Fe(C(SCH₃)2)]⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)(CO)(P(C₆H₅)3)Fe(C(SCH₃)2)]PF₆
• CAS No.: 77781-40-9
• Molecular Formula: C₂₇H₂₆FeOPS₂*F₆P
• Molecular Weight: 662.42

Synonyms:[(C₅H₅)(CO)(P(C₆H₅)3)Fe(C(SCH₃)2)]⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)(CO)(P(C₆H₅)3)Fe(C(SCH₃)2)]PF₆

Chemical Property of [(C₅H₅)(CO)(P(C₆H₅)3)Fe(C(SCH₃)2)]⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)(CO)(P(C₆H₅)3)Fe(C(SCH₃)2)]PF₆

Chemical Property:

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Technology Process of [(C₅H₅)(CO)(P(C₆H₅)3)Fe(C(SCH₃)2)]⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)(CO)(P(C₆H₅)3)Fe(C(SCH₃)2)]PF₆

There total 1 articles about [(C₅H₅)(CO)(P(C₆H₅)3)Fe(C(SCH₃)2)]⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)(CO)(P(C₆H₅)3)Fe(C(SCH₃)2)]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

{CpFe(CO)(MeCN){=C(SMe)2}}PF6 → [(C5H5)(CO)(P(C6H5)3)Fe(C(SCH3)2)](1+)*PF6(1-)=[(C5H5)(CO)(P(C6H5)3)Fe(C(SCH3)2)]PF6 (77781-40-9)

Guidance literature:

With PPh₃; In dichloromethane; byproducts: CH3CN; a soln. of Fe-complex and ligand in CH2Cl2 was stirred for 5 h at room temp. under N2; evapd., washed with Et2O, crystd. from CH2Cl2 with Et2O at -20°C; elem. anal.;

DOI:10.1016/S0022-328X(00)82939-3

Reference yield: 62.0%

[(C5H5)(CO)(P(C6H5)3)Fe(C(SCH3)2)](1+)*PF6(1-)=[(C5H5)(CO)(P(C6H5)3)Fe(C(SCH3)2)]PF6 (77781-40-9) → (C5H5)(CO)(P(C6H5)3)FeCH(SCH3)2 (85629-24-9)

Guidance literature:

With (Et₃BH)Li; In tetrahydrofuran; (N2); (Et3BH)Li added dropwise to Fe complex soln., allowed to react for 30 min; solvent removed (vac.), residue extd. (hexane/Et2O), evapd.;

DOI:10.1021/om50002a014

Reference yield:

[(C5H5)(CO)(P(C6H5)3)Fe(C(SCH3)2)](1+)*PF6(1-)=[(C5H5)(CO)(P(C6H5)3)Fe(C(SCH3)2)]PF6 (77781-40-9) + benzylamine (100-46-9) → (C5H5)(CO)(P(C6H5)3)Fe(CNCH2C6H5)(1+)*PF6(1-)=[(C5H5)(CO)(P(C6H5)3)Fe(CNCH2C6H5)]PF6 (77781-54-5)

Guidance literature:

In acetonitrile; byproducts: CH3SH; a soln. of Fe-complex and ligand in CH3CN was stirred;

DOI:10.1016/S0022-328X(00)82939-3

Downstream raw materials:

(C₅H₅)(CO)(P(C₆H₅)3)FeCH(SCH₃)2

(C₅H₅)(CO)(P(C₆H₅)3)Fe(CNCH₂C₆H₅)⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)(CO)(P(C₆H₅)3)Fe(CNCH₂C₆H₅)]PF₆

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