[(1,1,1-tris((diphenylphosphino)methyl)ethane)Ni(S₂COEt)]BPh₄

Base Information

• Chemical Name: [(1,1,1-tris((diphenylphosphino)methyl)ethane)Ni(S₂COEt)]BPh₄
• CAS No.: 83561-97-1
• Molecular Formula: C₂₄H₂₀B*C₄₄H₄₄NiOP₃S₂
• Molecular Weight: 1123.81
• Mol file: 83561-97-1.mol

Synonyms:[(1,1,1-tris((diphenylphosphino)methyl)ethane)Ni(S₂COEt)]BPh₄

Chemical Property of [(1,1,1-tris((diphenylphosphino)methyl)ethane)Ni(S₂COEt)]BPh₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of [(1,1,1-tris((diphenylphosphino)methyl)ethane)Ni(S₂COEt)]BPh₄

There total 1 articles about [(1,1,1-tris((diphenylphosphino)methyl)ethane)Ni(S₂COEt)]BPh₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

nickel(II) tetrafluoroborate hexahydrate + potassium ethyl xanthogenate (140-89-6) + sodium tetraphenyl borate (143-66-8) + [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] (22031-12-5) → [(1,1,1-tris((diphenylphosphino)methyl)ethane)Ni(S2COEt)]BPh4 (83561-97-1)

Guidance literature:

In ethanol; dichloromethane; acetone; KS2COC2H5/EtOH added under N2 to mixt. of Ni(BF4)2*6H2O in EtOH, ligandin CH2Cl2 and NaB(C6H5)4 in acetone;

Reference yield: 50.0%

[(1,1,1-tris((diphenylphosphino)methyl)ethane)Ni(S2COEt)]BPh4 (83561-97-1) → Ni(CO)CH3C{CH2P(C6H5)2}3 (14876-51-8)

Guidance literature:

With NaBH₄; In ethanol; acetone; (N2); Ni complex suspn. in acetone treated with excess of NaBH4/EtOH; left standing for 1 h; elem. anal.;

upstream raw materials:

potassium ethyl xanthogenate

sodium tetraphenyl borate

[2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine]

Downstream raw materials:

Ni(CO)CH₃C{CH₂P(C₆H₅)2}3