{P,P-diphenyl-bis(N-trimethylsilylimino)phosphinato}lithium

Base Information

• Chemical Name: {P,P-diphenyl-bis(N-trimethylsilylimino)phosphinato}lithium
• CAS No.: 22846-25-9
• Molecular Formula: C₁₈H₂₈N₂PSi₂*Li
• Molecular Weight: 366.519
• Mol file: 22846-25-9.mol

Synonyms:{P,P-diphenyl-bis(N-trimethylsilylimino)phosphinato}lithium

Chemical Property of {P,P-diphenyl-bis(N-trimethylsilylimino)phosphinato}lithium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {P,P-diphenyl-bis(N-trimethylsilylimino)phosphinato}lithium

There total 1 articles about {P,P-diphenyl-bis(N-trimethylsilylimino)phosphinato}lithium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ {P,P-diphenyl-bis(N-trimethylsilylimino)phosphinato}lithium (22846-25-9)

Guidance literature:

Reference yield: 92.0%

{P,P-diphenyl-bis(N-trimethylsilylimino)phosphinato}lithium (22846-25-9) → C33H47ClN4P2Si3Te

Guidance literature:

With tellurium tetrachloride; In dichloromethane;

Reference yield: 92.0%

(di-μ-chloro)bis{(η8-cyclooctatetraenyl)bis(tetrahydrofurane)cerium(III)} + {P,P-diphenyl-bis(N-trimethylsilylimino)phosphinato}lithium (22846-25-9) → (C8H8)Ce{(C6H5)2P(NSi(CH3)3)2}(C4H8O) (148390-08-3)

Guidance literature:

In tetrahydrofuran; byproducts: LiCl; (N2); dropwise addn. of soln. of org. compd. to suspn. of Ce-complex (-10°C), stirring (10 min at -10°C, 12 h at room temp.); solvent evapn. (vac.), extn. (toluol), filtration (Celite), evapn. (vac.);

DOI:10.1016/0022-328X(93)83086-B

Downstream raw materials:

trans-{Ph₂P(NSiMe₃)2}2Yb(THF)2

(C₈H₈)Sm{(C₆H₅)2P(NSi(CH₃)3)2}(C₄H₈O)

(C₈H₈)Pr{(C₆H₅)2P(NSi(CH₃)3)2}(C₄H₈O)

(C₈H₈)Ce{(C₆H₅)2P(NSi(CH₃)3)2}(C₄H₈O)