5,5'-bis[3-hexyloxymethyl-5-(trimethylsilanyl)phenyl]-2,2'-bipyridinyl

Base Information

Chemical Name:5,5'-bis[3-hexyloxymethyl-5-(trimethylsilanyl)phenyl]-2,2'-bipyridinyl
CAS No.:851605-32-8
Molecular Formula:C₄₂H₆₀N₂O₂Si₂
Molecular Weight:681.122
Hs Code.:

Synonyms:5,5'-bis[3-hexyloxymethyl-5-(trimethylsilanyl)phenyl]-2,2'-bipyridinyl

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Chemical Property of 5,5'-bis[3-hexyloxymethyl-5-(trimethylsilanyl)phenyl]-2,2'-bipyridinyl

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Technology Process of 5,5'-bis[3-hexyloxymethyl-5-(trimethylsilanyl)phenyl]-2,2'-bipyridinyl

There total 4 articles about 5,5'-bis[3-hexyloxymethyl-5-(trimethylsilanyl)phenyl]-2,2'-bipyridinyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 15862-18-7
5,5'-dibromo-2,2'-dipyridyl

: 276670-17-8
2-(3-Hexyloxymethyl-5-trimethylsilanylphenyl)-4,4,5,5-tetramethyl-[1,3,2]-dioxaborolane

: 851605-32-8
5,5'-bis[3-hexyloxymethyl-5-(trimethylsilanyl)phenyl]-2,2'-bipyridinyl

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In toluene; for 72h; Reflux;
DOI:10.1021/ol800316b

Reference yield: 85.0%

: 851605-33-9
2-bromo-5-[3-hexyloxymethyl-5-(trimethylsilanyl)phenyl]-pyridine

: 851605-32-8
5,5'-bis[3-hexyloxymethyl-5-(trimethylsilanyl)phenyl]-2,2'-bipyridinyl

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; bis(tri-n-butyltin); In toluene; for 120h;
DOI:10.1002/ejoc.200400744

Reference yield:

: 73290-22-9
2-bromo-5-iodo-pyridine

: 851605-32-8
5,5'-bis[3-hexyloxymethyl-5-(trimethylsilanyl)phenyl]-2,2'-bipyridinyl

Guidance literature:: Multi-step reaction with 2 steps

1.1: Bu₄NBr; Na₂CO₃; [Pd(PPh₃)4] / toluene; H₂O / 96 h / Heating

2.1: BuLi; Me₃SnCl / toluene; hexane / -78 - 20 °C

2.2: 0.43 g / [Pd(PPh₃)4] / toluene / 120 h / Heating

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; trimethyltin(IV)chloride; tetrabutylammomium bromide; sodium carbonate; In hexane; water; toluene;
DOI:10.1002/ejoc.200400744