3-Methyl-1-phenyl-1H-phosphole; compound with trifluoro-methanesulfonic acid

Base Information

• Chemical Name: 3-Methyl-1-phenyl-1H-phosphole; compound with trifluoro-methanesulfonic acid
• CAS No.: 104629-25-6
• Molecular Formula: CHF₃O₃S*C₁₁H₁₁P
• Molecular Weight: 324.26
• Mol file: 104629-25-6.mol

Synonyms:3-Methyl-1-phenyl-1H-phosphole; compound with trifluoro-methanesulfonic acid

Chemical Property of 3-Methyl-1-phenyl-1H-phosphole; compound with trifluoro-methanesulfonic acid

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 3-Methyl-1-phenyl-1H-phosphole; compound with trifluoro-methanesulfonic acid

There total 1 articles about 3-Methyl-1-phenyl-1H-phosphole; compound with trifluoro-methanesulfonic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trifluorormethanesulfonic acid (1493-13-6) + 3-methyl-1-phenylphosphole (30540-42-2) → 3-Methyl-1-phenyl-1H-phosphole; compound with trifluoro-methanesulfonic acid (104629-25-6)

Guidance literature:

In dichloromethane-d2; at -70 ℃;

Reference yield:

3-Methyl-1-phenyl-1H-phosphole; compound with trifluoro-methanesulfonic acid (104629-25-6) → 2,5-dihydro-3-methyl-1-phenyl-1H-phosphole 1-oxide (7564-51-4)

Guidance literature:

Multi-step reaction with 2 steps

1: Et₃N*HCl / CH₂Cl₂ / 0.5 h / -70 °C

2: water / CD₂Cl₂ / 0.5 h

With water; triethylamine hydrochloride; In dichloromethane; dichloromethane-d2;

Reference yield:

3-Methyl-1-phenyl-1H-phosphole; compound with trifluoro-methanesulfonic acid (104629-25-6) → 1-chloro-3-methyl-1-phenylphosphol-3-enium chloride (104629-24-5)

Guidance literature:

With triethylamine hydrochloride; In dichloromethane; at -70 ℃; for 0.5h;

upstream raw materials:

trifluorormethanesulfonic acid

3-methyl-1-phenylphosphole

Downstream raw materials:

1-chloro-3-methyl-1-phenylphosphol-3-enium chloride

2,5-dihydro-3-methyl-1-phenyl-1H-phosphole 1-oxide