(3-nitrophenyl)(triphenyl-λ5-phosphanyl)gold

Base Information

• Chemical Name: (3-nitrophenyl)(triphenyl-λ5-phosphanyl)gold
• CAS No.: 87961-72-6
• Molecular Formula: C₂₄H₁₉AuNO₂P
• Molecular Weight: 581.361
• Mol file: 87961-72-6.mol

Synonyms:(3-nitrophenyl)(triphenyl-λ5-phosphanyl)gold

Chemical Property of (3-nitrophenyl)(triphenyl-λ5-phosphanyl)gold

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (3-nitrophenyl)(triphenyl-λ5-phosphanyl)gold

There total 3 articles about (3-nitrophenyl)(triphenyl-λ5-phosphanyl)gold which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + m-nitrobenzene boronic acid (13331-27-6) → (3-nitrophenyl)(triphenyl-λ5-phosphanyl)gold (87961-72-6)

Guidance literature:

With Cs₂CO₃; In isopropyl alcohol; (Ar); addn. of Cs2CO3 and then gold compd. to soln. of phenylboronic acid deriv. in dry isopropanol, stirring at 50°C for 24 h; A.S.K. Hashmi, T.D. Ramamurthi and F. Rominger, J. Organomet. Chem., 2009, 694, 592; evapn. in vac., extn. (benzene), filtration through celite, evapn. in vac., washing with pentane, drying, extn. (benzene), filtration, washing with pentane, drying in high vac., NMR and MS;

DOI:10.1039/c2ob06788a

Reference yield: 60.0%

[BzPh3P][Au(m-nitrophenyl)Cl] (87961-64-6) → (3-nitrophenyl)(triphenyl-λ5-phosphanyl)gold (87961-72-6)

Guidance literature:

With PPh₃; In acetone; to soln. of educt in acetone added soln. of PPh3 in acetone; concd., Et2O added, filtered, concd., n-hexane added; elem. anal.;

DOI:10.1016/0022-328X(83)80090-4

Reference yield:

bis(m-nitrophenyl)mercury (26953-06-0) → (3-nitrophenyl)(triphenyl-λ5-phosphanyl)gold (87961-72-6)

Guidance literature:

Multi-step reaction with 2 steps

1: acetone

2: PPh₃ / acetone

With PPh₃; In acetone;

DOI:10.1016/0022-328X(83)80090-4

upstream raw materials:

[BzPh₃P][Au(m-nitrophenyl)Cl]

(triphenylphosphine)gold(I) chloride

m-nitrobenzene boronic acid

bis(m-nitrophenyl)mercury

Downstream raw materials:

dicarbonylcyclopentadienyl(m-nitrophenyl)iron

3'-nitro-[1,1'-biphenyl]-4-yl-amine

(E)-1-(3,7-dimethylocta-2,6-dien-1-yl)-3-nitrobenzene

m-nitrobromobenzene