Diphenyliodonium-2-carboxylate

Base Information

• Chemical Name: Diphenyliodonium-2-carboxylate
• CAS No.: 1488-42-2
• Deprecated CAS: 109545-72-4
• Molecular Formula: C13H9IO2
• Molecular Weight: 324.118
• European Community (EC) Number: 216-070-2
• NSC Number: 86229
• DSSTox Substance ID: DTXSID2061725
• Wikidata: Q72473265
• Mol file: 1488-42-2.mol

Synonyms:Diphenyliodonium-2-carboxylate;1488-42-2;2-(phenyliodonio)benzoate;2-phenyliodoniobenzoate;DIPHENYL IODONIUM-2-CARBOXYLATE;Iodonium, (2-carboxyphenyl)phenyl-, inner salt;(2-Carboxylatophenyl)phenyliodonium;NSC 86229;109545-72-4;AI3-62156;EINECS 216-070-2;Iodonium, (2-carboxyphenyl)phenyl-, hydroxide, innersalt;Iodonium, (2-carboxyphenyl)phenyl-, hydroxide, inner salt;Iodonium, (o-carboxyphenyl)phenyl-, hydroxide, inner salt;C13-H9-I-O2;(2-Carboxyphenyl)phenyliodonium Hydroxide Inner Salt;iodonium,(2-carboxyphenyl)phenyl-,hydroxide,innersalt;SCHEMBL1716369;Iodonium, hydroxide, inner salt;DTXSID2061725;(2-carboxyphenyl)(phenyl)iodanium;NSC86229;MFCD00032129;NSC-86229;AKOS024405829;AS-10310;AM20030016;CS-0156596;D2503;FT-0625272;A884324;EN300-18535328;DIPHENYLIODONIUM-2-CARBOXYLATE MONOHYDRATE, 98+per cent

Chemical Property of Diphenyliodonium-2-carboxylate

Chemical Property:

• Melting Point: 226oC
• PSA: 40.13000
• LogP: -1.82150
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• XLogP3: 4.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 323.96473
• Heavy Atom Count: 16
• Complexity: 231

Purity/Quality:

98%min ^*data from raw suppliers

Iodonium (2-carboxyphenyl)phenyl-hydroxideinnersalt95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R36/37/38:Irritating to eyes, respiratory system and skin.
• Hazard Codes: R36/37/38:Irritating to eyes, respiratory system and skin.
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[I+]C2=CC=CC=C2C(=O)[O-]

Technology Process of Diphenyliodonium-2-carboxylate

There total 5 articles about Diphenyliodonium-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

2-Iodobenzoic acid (88-67-5) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → Diphenyliodonium-2-carboxylate (1488-42-2,109545-72-4)

Guidance literature:

2-Iodobenzoic acid; With dipotassium peroxodisulfate; sulfuric acid; for 0.5h; Cooling with ice;

benzene; at 20 ℃; for 5h;

Reference yield:

2-Iodobenzoic acid (88-67-5) → Diphenyliodonium-2-carboxylate (1488-42-2,109545-72-4)

Guidance literature:

Multi-step reaction with 2 steps

1: H₂SO₄, HNO₃

2: (i) H₂SO₄, (ii) aq. NaOH

With sulfuric acid; nitric acid;

DOI:10.1021/jo01025a049

Reference yield:

(2-carboxy-phenyl)-phenyl-iodonium ; iodide (109185-34-4) → Diphenyliodonium-2-carboxylate (1488-42-2,109545-72-4)

Guidance literature:

With sodium hydroxide;

DOI:10.1021/ja01488a056

upstream raw materials:

2-Iodobenzoic acid

benzene

(2-carboxy-phenyl)-phenyl-iodonium ; iodide

o-iodosobenzoic acid

Downstream raw materials:

1,2-Diiodobenzene

2-benzo[1,2,5]thiadiazol-4-ylamino-benzoic acid

2-<(2-carboxyphenyl)amino>benzenesulfonic acid

5'-nitro-2'-chloro-2-carboxy-diphenylamine

Refernces

• 1、 -. "Process for preparing n-alkylanilines and n-allylanilines". . . Retrieved 2008/06/13.
• 2、 -. "Selective chlorination of ortho-substituted phenols". . . Retrieved 2008/06/13.