(+)-(1R,5R,6S)-1-benzyl-2-methylene-6-[(S)-4-phenyl-2-oxo-1,3-oxazolidin-3-yl]carbapenam

Base Information

• Chemical Name: (+)-(1R,5R,6S)-1-benzyl-2-methylene-6-[(S)-4-phenyl-2-oxo-1,3-oxazolidin-3-yl]carbapenam
• CAS No.: 164354-48-7
• Molecular Formula: C₂₃H₂₂N₂O₃
• Molecular Weight: 374.439

Synonyms:(+)-(1R,5R,6S)-1-benzyl-2-methylene-6-[(S)-4-phenyl-2-oxo-1,3-oxazolidin-3-yl]carbapenam

Chemical Property of (+)-(1R,5R,6S)-1-benzyl-2-methylene-6-[(S)-4-phenyl-2-oxo-1,3-oxazolidin-3-yl]carbapenam

Chemical Property:

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Technology Process of (+)-(1R,5R,6S)-1-benzyl-2-methylene-6-[(S)-4-phenyl-2-oxo-1,3-oxazolidin-3-yl]carbapenam

There total 2 articles about (+)-(1R,5R,6S)-1-benzyl-2-methylene-6-[(S)-4-phenyl-2-oxo-1,3-oxazolidin-3-yl]carbapenam which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

(1R,5R,6S)-1-benzyl-2-(Z)-tributylstannylmethylene-6-[(S)-4-phenyl-2-oxo-1,3-oxazolidin-3-yl]carbapenam → (+)-(1R,5R,6S)-1-benzyl-2-methylene-6-[(S)-4-phenyl-2-oxo-1,3-oxazolidin-3-yl]carbapenam (164354-48-7)

Guidance literature:

With toluene-4-sulfonic acid; In dichloromethane; at 20 ℃;

DOI:10.1021/jo9823994

Reference yield: 90.0%

(1R,5R,6S)-1-benzyl-2-(Z)-triphenylstannylmethylene-6-[(S)-4-phenyl-2-oxo-1,3-oxazolidin-3-yl]carbapenam → (+)-(1R,5R,6S)-1-benzyl-2-methylene-6-[(S)-4-phenyl-2-oxo-1,3-oxazolidin-3-yl]carbapenam (164354-48-7)

Guidance literature:

With toluene-4-sulfonic acid; In dichloromethane; at 20 ℃;

DOI:10.1021/jo9823994

Reference yield: 60.0%

(+)-(1R,5R,6S)-1-benzyl-2-methylene-6-[(S)-4-phenyl-2-oxo-1,3-oxazolidin-3-yl]carbapenam (164354-48-7) → (+)-(1S,5R,6S)-1-benzyl-2-oxo-6-[(S)-4-phenyl-2-oxo-1,3-oxazolidin-3-yl]carbapenam

Guidance literature:

(+)-(1R,5R,6S)-1-benzyl-2-methylene-6-[(S)-4-phenyl-2-oxo-1,3-oxazolidin-3-yl]carbapenam; With ozone; In dichloromethane; at -78 ℃;

With dimethylsulfide; In dichloromethane; at 20 ℃;

DOI:10.1021/jo9823994

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