Technology Process of Ni(PCH3(C6H5)2)2(C6F4C6F4H)Br
There total 1 articles about Ni(PCH3(C6H5)2)2(C6F4C6F4H)Br which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
n-butyl lithium;
In
tetrahydrofuran;
addn. of nBuLi to cooled biphenyl soln. via syringe, -78°C; stirring slurry, -78°C, 15 min; addn. to Ni complex suspension; cooling to 0°C; stirring, 0°C, 1h; stirring, room temp., 21h; concentrating; addn. of MeOH; pptn.; cooling to 0°C; stirring, 1h; filtration, washing (methanol, hexanes); air-drying; recrystn. (CH2Cl2/hexanes); drying (vac.); elem. anal.;
- Guidance literature:
-
With
n-butyl lithium;
In
tetrahydrofuran;
addn. of nBuLi to cooled biphenyl soln. via syringe, -78°C; stirring, -78°C, 30 min; addn. to Ni complex suspension at 0°C; stirring, 0°C, 1h, then at room temp., 24h; evapn.; stirring with methanol, 30 min; filtration; washing (methanol); drying (vac.); elem. anal.;
- Guidance literature:
-
With
n-butyl lithium;
In
tetrahydrofuran;
addn. of nBuLi to cooled biphenyl soln. via syringe, -78°C; stirring slurry, -78°C, 15 min; addn. to Ni complex suspension at 0°C; stirring, 0°C, 1h, then at room temp., 45h; concentrating; addn. of methanol; pptn.; stirring, 4h; removing supernatant via cannula; washing (methanol); drying in a stream of N2, then in vac.;
