Technology Process of C36H41O12N3
There total 13 articles about C36H41O12N3 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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Multi-step reaction with 10 steps
1.1: diisopropylamine; nBuLi / tetrahydrofuran; hexane / 0.25 h / -78 °C
1.2: 83 percent / HMPA / tetrahydrofuran; hexane / 1 h / -40 °C
2.1: 76 percent / PPTS / ethanol / 10 h / 20 °C
3.1: 4 Angstroem MS; PhSOTf; DTBP / CH2Cl2 / 2 h / -78 - -40 °C
4.1: 87 percent / RuCl3*H2O; NaIO4 / ethyl acetate; acetonitrile; H2O
5.1: pyridine / CH2Cl2
6.1: CsOCOCF3; 18-crown-6 / toluene; dimethylformamide / 80 °C
7.1: 64 percent / imidazole / CH2Cl2
8.1: pyridine / CH2Cl2
9.1: Bu4NN3 / toluene
10.1: 68 percent / trifluoroacetic acid / methanol
With
pyridine; 1H-imidazole; ruthenium trichloride; sodium periodate; n-butyllithium; 18-crown-6 ether; di-tert-butyl peroxide; 4 Angstroem MS; tetrabutylammoniun azide; pyridinium p-toluenesulfonate; diisopropylamine; trifluoroacetic acid;
In
tetrahydrofuran; methanol; ethanol; hexane; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide; toluene; acetonitrile;
DOI:10.1021/ol990245k
- Guidance literature:
-
Multi-step reaction with 9 steps
1: 76 percent / PPTS / ethanol / 10 h / 20 °C
2: 4 Angstroem MS; PhSOTf; DTBP / CH2Cl2 / 2 h / -78 - -40 °C
3: 87 percent / RuCl3*H2O; NaIO4 / ethyl acetate; acetonitrile; H2O
4: pyridine / CH2Cl2
5: CsOCOCF3; 18-crown-6 / toluene; dimethylformamide / 80 °C
6: 64 percent / imidazole / CH2Cl2
7: pyridine / CH2Cl2
8: Bu4NN3 / toluene
9: 68 percent / trifluoroacetic acid / methanol
With
pyridine; 1H-imidazole; ruthenium trichloride; sodium periodate; 18-crown-6 ether; di-tert-butyl peroxide; 4 Angstroem MS; tetrabutylammoniun azide; pyridinium p-toluenesulfonate; trifluoroacetic acid;
In
methanol; ethanol; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide; toluene; acetonitrile;
DOI:10.1021/ol990245k