(2Z)-1-((tert-butyloxycarbonyl)oxy)-6-(tert-butyldiphenylsiloxy)-2-((E)-7-methoxy-4-methyl-8,8-diphenyloct-3-enyl)hex-2-ene

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Chemical Name:(2Z)-1-((tert-butyloxycarbonyl)oxy)-6-(tert-butyldiphenylsiloxy)-2-((E)-7-methoxy-4-methyl-8,8-diphenyloct-3-enyl)hex-2-ene
CAS No.:1312080-31-1
Molecular Formula:C₄₉H₆₄O₅Si
Molecular Weight:761.13
Hs Code.:

Synonyms:(2Z)-1-((tert-butyloxycarbonyl)oxy)-6-(tert-butyldiphenylsiloxy)-2-((E)-7-methoxy-4-methyl-8,8-diphenyloct-3-enyl)hex-2-ene

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Chemical Property of (2Z)-1-((tert-butyloxycarbonyl)oxy)-6-(tert-butyldiphenylsiloxy)-2-((E)-7-methoxy-4-methyl-8,8-diphenyloct-3-enyl)hex-2-ene

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Technology Process of (2Z)-1-((tert-butyloxycarbonyl)oxy)-6-(tert-butyldiphenylsiloxy)-2-((E)-7-methoxy-4-methyl-8,8-diphenyloct-3-enyl)hex-2-ene

There total 9 articles about (2Z)-1-((tert-butyloxycarbonyl)oxy)-6-(tert-butyldiphenylsiloxy)-2-((E)-7-methoxy-4-methyl-8,8-diphenyloct-3-enyl)hex-2-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 1312080-29-7
(E)-7-methoxy-4-methyl-8,8-diphenylocta-1,3-diene

: 1312080-30-0
tert-butyl (2E)-6-((tert-butyldiphenylsilyl)oxy)-2-iodohex-2-en-1-yl carbonate

: 1312080-31-1
(2Z)-1-((tert-butyloxycarbonyl)oxy)-6-(tert-butyldiphenylsiloxy)-2-((E)-7-methoxy-4-methyl-8,8-diphenyloct-3-enyl)hex-2-ene

Guidance literature:: (E)-7-methoxy-4-methyl-8,8-diphenylocta-1,3-diene; With 9-borabicyclo[3.3.1]nonane dimer; In tetrahydrofuran; at 20 ℃; for 2h; Inert atmosphere;

tert-butyl (2E)-6-((tert-butyldiphenylsilyl)oxy)-2-iodohex-2-en-1-yl carbonate; With potassium phosphate; bis(tri-t-butylphosphine)palladium⁽⁰⁾; In tetrahydrofuran; water; for 72h; Inert atmosphere;
DOI:10.1002/anie.201007757

Reference yield:

: 1312080-46-8
(E)-6-(tert-butyldiphenylsiloxy)-2-iodohex-2-en-1-ol

: 1312080-31-1
(2Z)-1-((tert-butyloxycarbonyl)oxy)-6-(tert-butyldiphenylsiloxy)-2-((E)-7-methoxy-4-methyl-8,8-diphenyloct-3-enyl)hex-2-ene

Guidance literature:: Multi-step reaction with 2 steps

1.1: 1-methyl-1H-imidazole / toluene / 0 - 20 °C / Inert atmosphere

2.1: 9-borabicyclo[3.3.1]nonane dimer / tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

2.2: 72 h / Inert atmosphere

With 1-methyl-1H-imidazole; 9-borabicyclo[3.3.1]nonane dimer; In tetrahydrofuran; toluene; 2.2: Suzuki coupling;
DOI:10.1002/anie.201007757

Reference yield:

: 1312080-45-7
(E)-5-methyl-1,1-diphenylocta-5,7-dien-2-ol

: 1312080-31-1
(2Z)-1-((tert-butyloxycarbonyl)oxy)-6-(tert-butyldiphenylsiloxy)-2-((E)-7-methoxy-4-methyl-8,8-diphenyloct-3-enyl)hex-2-ene

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydride / N,N-dimethyl-formamide / 0.67 h / 0 °C / Inert atmosphere

1.2: 16 h / 20 °C / Inert atmosphere

2.1: 9-borabicyclo[3.3.1]nonane dimer / tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

2.2: 72 h / Inert atmosphere

With 9-borabicyclo[3.3.1]nonane dimer; sodium hydride; In tetrahydrofuran; N,N-dimethyl-formamide; 2.2: Suzuki coupling;
DOI:10.1002/anie.201007757