Dimolybdenum,tetrakis(mu-(6-methyl-2(1H)-pyridinonato-)

Base Information

Chemical Name:Dimolybdenum,tetrakis(mu-(6-methyl-2(1H)-pyridinonato-)
CAS No.:67634-80-4
Molecular Formula:C₂₄H₂₄Mo₂N₄O₄
Molecular Weight:624.359
Hs Code.:

Synonyms:

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Chemical Property of Dimolybdenum,tetrakis(mu-(6-methyl-2(1H)-pyridinonato-)

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MSDS Files:: SDS file from LookChem

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Technology Process of Dimolybdenum,tetrakis(mu-(6-methyl-2(1H)-pyridinonato-)

There total 1 articles about Dimolybdenum,tetrakis(mu-(6-methyl-2(1H)-pyridinonato-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 17.0%

: 17084-13-8
potassium hexafluorophosphate

: cis-{Mo2(μ-2-hydroxy-6-methylpyridine)2Cl2(P(C6H5)2CH3)2}

: 119072-55-8,7188-38-7
tert-butylisonitrile

: 67634-80-4
{Mo₂(2-hydroxy-6-methylpyridine)4}

: {Mo(PCH₃(C₆H₅)2)2(CNC(CH₃)3)5}⁽²⁺⁾*2PF₆^(1-)={Mo(PCH₃(C₆H₅)2)2(CNC(CH₃)3)5}(PF₆)2

Guidance literature:: In methanol; dry N2-atm.; stoichiometric ratio (Mo2(C5H3N(CH3)O)2Cl2(PCH3(C6H5)2 / CNC(CH3)3) 1:12; hot methanol (18 h);; cooling; filtration (from pptd. Mo2(C5H3N(CH3)O)4); addn. of excess KPF6 to orange filtrate; stirring (1 h); evapn. to dryness; extraction (CH2Cl2); filtration; dropwise addn. of diethylether (or diethylether - petroleum ether mixtures);;
DOI:10.1016/S0277-5387(00)84879-2

Reference yield: 62.0%

: 67634-80-4
{Mo₂(2-hydroxy-6-methylpyridine)4}

: 49623-71-4
2,4,6-triisopropylbenzoic acid

: 942951-13-5
[Mo₂(2-hydroxy-6-methylpyridine(-1H))2(2,4,6-triisopropylbenzoato)2]

Guidance literature:: In toluene; under Ar; mixt. of Mo complex and (i-Pr)3C6H2CO2H (4 equiv.) in toluene stirred at 60°C (oil bath) for 24 h; cooled to room temp.; solid collected on frit; washed with hexanes; dried under vac.; detd. by(1)H NMR and mass spectra;
DOI:10.1039/b618957a