(4S,5S)-4,8-Bis-(3,5-bis-trifluoromethyl-phenyl)-6-(2,2-dimethyl-4-phenyl-[1,3]dioxan-5-yl)-5H-dibenzo[c,e]azepinium tetraphenylborate

Base Information

Chemical Name:(4S,5S)-4,8-Bis-(3,5-bis-trifluoromethyl-phenyl)-6-(2,2-dimethyl-4-phenyl-[1,3]dioxan-5-yl)-5H-dibenzo[c,e]azepinium tetraphenylborate
CAS No.:1417577-02-6
Molecular Formula:C₂₄H₂₀B*C₄₂H₃₀F₁₂NO₂
Molecular Weight:1127.92
Hs Code.:

Synonyms:(4S,5S)-4,8-Bis-(3,5-bis-trifluoromethyl-phenyl)-6-(2,2-dimethyl-4-phenyl-[1,3]dioxan-5-yl)-5H-dibenzo[c,e]azepinium tetraphenylborate

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Chemical Property of (4S,5S)-4,8-Bis-(3,5-bis-trifluoromethyl-phenyl)-6-(2,2-dimethyl-4-phenyl-[1,3]dioxan-5-yl)-5H-dibenzo[c,e]azepinium tetraphenylborate

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Technology Process of (4S,5S)-4,8-Bis-(3,5-bis-trifluoromethyl-phenyl)-6-(2,2-dimethyl-4-phenyl-[1,3]dioxan-5-yl)-5H-dibenzo[c,e]azepinium tetraphenylborate

There total 3 articles about (4S,5S)-4,8-Bis-(3,5-bis-trifluoromethyl-phenyl)-6-(2,2-dimethyl-4-phenyl-[1,3]dioxan-5-yl)-5H-dibenzo[c,e]azepinium tetraphenylborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 1417577-04-8
(4S,5S)-4,8-Bis-(3,5-bis-trifluoromethyl-phenyl)-6-(2,2-dimethyl-4-phenyl-[1,3]dioxan-5-yl)-6,7-dihydro-5H-dibenzo[c,e]azepine

: 143-66-8
sodium tetraphenyl borate

: 1417577-02-6
(4S,5S)-4,8-Bis-(3,5-bis-trifluoromethyl-phenyl)-6-(2,2-dimethyl-4-phenyl-[1,3]dioxan-5-yl)-5H-dibenzo[c,e]azepinium tetraphenylborate

Guidance literature:: (4S,5S)-4,8-Bis-(3,5-bis-trifluoromethyl-phenyl)-6-(2,2-dimethyl-4-phenyl-[1,3]dioxan-5-yl)-6,7-dihydro-5H-dibenzo[c,e]azepine; With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); In tetrachloromethane; for 3h;

sodium tetraphenyl borate; In ethanol; acetonitrile; at 20 ℃; for 0.0833333h;
DOI:10.1016/j.tet.2012.10.076

Reference yield:

: 1417577-03-7
3,3'-bis-(3,5-(trifluoromethyl)phenyl)-2,2'-dimethyl-1,1'-biphenyl

: 1417577-02-6
(4S,5S)-4,8-Bis-(3,5-bis-trifluoromethyl-phenyl)-6-(2,2-dimethyl-4-phenyl-[1,3]dioxan-5-yl)-5H-dibenzo[c,e]azepinium tetraphenylborate

Guidance literature:: Multi-step reaction with 3 steps

1.1: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / tetrachloromethane / 3 h / 20 °C / Reflux

2.1: potassium carbonate / acetonitrile / 16 h / 20 °C / Reflux

3.1: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / tetrachloromethane / 3 h

3.2: 0.08 h / 20 °C

With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); potassium carbonate; In tetrachloromethane; acetonitrile;
DOI:10.1016/j.tet.2012.10.076

Reference yield:

: 916235-63-7
2,2'-Bis-bromomethyl-3,3'-bis-(3,5-(trifluoromethyl)phenyl)-1,1'-biphenyl

: 1417577-02-6
(4S,5S)-4,8-Bis-(3,5-bis-trifluoromethyl-phenyl)-6-(2,2-dimethyl-4-phenyl-[1,3]dioxan-5-yl)-5H-dibenzo[c,e]azepinium tetraphenylborate

Guidance literature:: Multi-step reaction with 2 steps

1.1: potassium carbonate / acetonitrile / 16 h / 20 °C / Reflux

2.1: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / tetrachloromethane / 3 h

2.2: 0.08 h / 20 °C

With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); potassium carbonate; In tetrachloromethane; acetonitrile;
DOI:10.1016/j.tet.2012.10.076