(2,4,6-triisopropylphenyl-SO₂NC₆H₄(CH₂NHSO₂-2,4,6-triisopropylphenyl)2)RhCl(triphenylphosphine)2

Base Information

• Chemical Name: (2,4,6-triisopropylphenyl-SO₂NC₆H₄(CH₂NHSO₂-2,4,6-triisopropylphenyl)2)RhCl(triphenylphosphine)2
• CAS No.: 1192062-06-8
• Molecular Formula: C₈₉H₁₀₉ClN₃O₆P₂RhS₃
• Molecular Weight: 1613.36

Synonyms:(2,4,6-triisopropylphenyl-SO₂NC₆H₄(CH₂NHSO₂-2,4,6-triisopropylphenyl)2)RhCl(triphenylphosphine)2

Chemical Property of (2,4,6-triisopropylphenyl-SO₂NC₆H₄(CH₂NHSO₂-2,4,6-triisopropylphenyl)2)RhCl(triphenylphosphine)2

Chemical Property:

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Technology Process of (2,4,6-triisopropylphenyl-SO₂NC₆H₄(CH₂NHSO₂-2,4,6-triisopropylphenyl)2)RhCl(triphenylphosphine)2

There total 1 articles about (2,4,6-triisopropylphenyl-SO₂NC₆H₄(CH₂NHSO₂-2,4,6-triisopropylphenyl)2)RhCl(triphenylphosphine)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

Wilkinson's catalyst (14694-95-2) + 1,6,11-tris[(2,4,6-triisopropylphenyl) sulfonamide]-1,6,11-triazaundeca-3,8-diyne → (2,4,6-triisopropylphenyl-SO2NC6H4(CH2NHSO2-2,4,6-triisopropylphenyl)2)RhCl(triphenylphosphine)2 (1192062-06-8)

Guidance literature:

In dichloromethane; byproducts: PPh3; under Ar; soln. of diyne and Rh complex in degassed CH2Cl2 stirred at room temp. for 5 h; degassed Et2O added; solvent evapd.;

DOI:10.1021/om900544u

Reference yield:

1,4-dihydroxybut-2-yne (110-65-6) + (2,4,6-triisopropylphenyl-SO2NC6H4(CH2NHSO2-2,4,6-triisopropylphenyl)2)RhCl(triphenylphosphine)2 (1192062-06-8) + triphenylphosphine (603-35-0) → Wilkinson's catalyst (14694-95-2)

Guidance literature:

With tetrabutylammonium tetrafluoroborate; In dichloromethane; byproducts: i-Pr3C6H2O2SNC8H4(CH2OH)2(CH2NHSO2C6H2-i-Pr3)2; under Ar; stoich. amt. of Rh complex and HOCH2C2CH2OH reacted in CH2Cl2 contg. n-Bu4NBF4 in presence of PPh3 (excess) at 25°C; monitored by cyclic voltammetry; Kinetics;

DOI:10.1021/om900544u

upstream raw materials:

Wilkinson's catalyst

Downstream raw materials:

Wilkinson's catalyst

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