<2R-(2R,4S,5R,8S)>-10-(Benzoyloxy)-5-hydroxy-4,6-dimethoxy-2,8-dimethyldecanoic acid methyl ester

Base Information

Chemical Name:<2R-(2R*,4S*,5R*,8S*)>-10-(Benzoyloxy)-5-hydroxy-4,6-dimethoxy-2,8-dimethyldecanoic acid methyl ester
CAS No.:118299-11-9
Molecular Formula:C₂₂H₃₄O₇
Molecular Weight:410.508
Hs Code.:

Synonyms:<2R-(2R*,4S*,5R*,8S*)>-10-(Benzoyloxy)-5-hydroxy-4,6-dimethoxy-2,8-dimethyldecanoic acid methyl ester

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Chemical Property of <2R-(2R*,4S*,5R*,8S*)>-10-(Benzoyloxy)-5-hydroxy-4,6-dimethoxy-2,8-dimethyldecanoic acid methyl ester

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Technology Process of <2R-(2R*,4S*,5R*,8S*)>-10-(Benzoyloxy)-5-hydroxy-4,6-dimethoxy-2,8-dimethyldecanoic acid methyl ester

There total 22 articles about <2R-(2R*,4S*,5R*,8S*)>-10-(Benzoyloxy)-5-hydroxy-4,6-dimethoxy-2,8-dimethyldecanoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: <4S-(2E,4R*,5S*,6R*,7E)>-10-Benzoyloxy-5-hydroxy-4,6-dimethoxy-2,8-dimethyl-2,7-decadienoic acid methyl ester

: 118299-11-9
<2R-(2R*,4S*,5R*,8S*)>-10-(Benzoyloxy)-5-hydroxy-4,6-dimethoxy-2,8-dimethyldecanoic acid methyl ester

Guidance literature:: With hydrogen; Rh-catalyst; In dichloromethane; for 5h; under 51714.8 Torr; Ambient temperature;
DOI:10.1021/jo00296a041

Reference yield:

: 118299-09-5
(E)-(2R,3R,4S)-3,8-Dihydroxy-2,4-dimethoxy-6-methyl-oct-5-enal

: 118299-11-9
<2R-(2R*,4S*,5R*,8S*)>-10-(Benzoyloxy)-5-hydroxy-4,6-dimethoxy-2,8-dimethyldecanoic acid methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: CH₂Cl₂ / from 0 deg C to RT

2: pyridine / tetrahydrofuran / Ambient temperature

3: 94 percent / H₂ / BF₄ (Evans catalyst) / CH₂Cl₂ / 51714.8 Torr / Ambient temperature

With pyridine; hydrogen; [(bicyclo[2.2.1]hepta-2,5-diene)(1,4-bis(diphenylphosphino)butane)rhodium(I)] tetrafluoroborate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00262a006

Reference yield:

: 126502-54-3
<4S-(2E,4R*,5S*,6R*,7E)>-5,10-Dihydroxy-4,6-dimethoxy-2,8-dimethyl-2,7-decadienoic acid methyl ester

: 118299-11-9
<2R-(2R*,4S*,5R*,8S*)>-10-(Benzoyloxy)-5-hydroxy-4,6-dimethoxy-2,8-dimethyldecanoic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine / tetrahydrofuran / Ambient temperature

2: 94 percent / H₂ / BF₄ (Evans catalyst) / CH₂Cl₂ / 51714.8 Torr / Ambient temperature

With pyridine; hydrogen; [(bicyclo[2.2.1]hepta-2,5-diene)(1,4-bis(diphenylphosphino)butane)rhodium(I)] tetrafluoroborate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00262a006