Technology Process of (E)-N-(2-nitrovinyl)-1,1-diphenylmethanimine
There total 4 articles about (E)-N-(2-nitrovinyl)-1,1-diphenylmethanimine which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
silver(I) nitrite; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical;
In
1,2-dichloro-ethane;
at 70 ℃;
for 18h;
Molecular sieve;
Sealed tube;
Inert atmosphere;
DOI:10.1021/acs.orglett.8b01518
- Guidance literature:
-
Multi-step reaction with 3 steps
1: triethylamine / dichloromethane / 0.5 h / 0 - 20 °C / Inert atmosphere
2: potassium tert-butylate / tetrahydrofuran / 1 h / 0 - 20 °C / Inert atmosphere
3: silver(I) nitrite; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical / 1,2-dichloro-ethane / 18 h / 70 °C / Molecular sieve; Sealed tube; Inert atmosphere
With
silver(I) nitrite; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; potassium tert-butylate; triethylamine;
In
tetrahydrofuran; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1021/acs.orglett.8b01518
- Guidance literature:
-
Multi-step reaction with 2 steps
1: potassium tert-butylate / tetrahydrofuran / 1 h / 0 - 20 °C / Inert atmosphere
2: silver(I) nitrite; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical / 1,2-dichloro-ethane / 18 h / 70 °C / Molecular sieve; Sealed tube; Inert atmosphere
With
silver(I) nitrite; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; potassium tert-butylate;
In
tetrahydrofuran; 1,2-dichloro-ethane;
DOI:10.1021/acs.orglett.8b01518
