C₄₂H₃₁NP₂

Base Information

• Chemical Name: C₄₂H₃₁NP₂
• CAS No.: 1345415-08-8
• Molecular Formula: C₄₂H₃₁NP₂
• Molecular Weight: 611.662
• Mol file: 1345415-08-8.mol

Synonyms:C₄₂H₃₁NP₂

Chemical Property of C₄₂H₃₁NP₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₄₂H₃₁NP₂

There total 4 articles about C₄₂H₃₁NP₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

3-bromo-9-(2-bromophenyl)-9H-carbazole (1345415-06-6) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → C42H31NP2 (1345415-08-8)

Guidance literature:

3-bromo-9-(2-bromophenyl)-9H-carbazole; With n-butyllithium; In tetrahydrofuran; hexane; Inert atmosphere; Cooling with acetone-dry ice;

chloro-diphenylphosphine; for 3h; Cooling with acetone-dry ice; Inert atmosphere;

DOI:10.1016/j.orgel.2011.03.015

Reference yield:

9-(2-bromophenyl)-9H-carbazole (902518-11-0) → C42H31NP2 (1345415-08-8)

Guidance literature:

Multi-step reaction with 2 steps

1.1: N-Bromosuccinimide / N,N-dimethyl-formamide / -20 - 20 °C / Inert atmosphere; Cooling with ice

2.1: n-butyllithium / tetrahydrofuran; hexane / Inert atmosphere; Cooling with acetone-dry ice

2.2: 3 h / Cooling with acetone-dry ice; Inert atmosphere

With N-Bromosuccinimide; n-butyllithium; In tetrahydrofuran; hexane; N,N-dimethyl-formamide;

DOI:10.1016/j.orgel.2011.03.015

Reference yield:

1-Bromo-2-iodobenzene (583-55-1) → C42H31NP2 (1345415-08-8)

Guidance literature:

Multi-step reaction with 3 steps

1.1: copper; potassium carbonate / 5,5-dimethyl-1,3-cyclohexadiene / 48 h / Inert atmosphere; Reflux

2.1: N-Bromosuccinimide / N,N-dimethyl-formamide / -20 - 20 °C / Inert atmosphere; Cooling with ice

3.1: n-butyllithium / tetrahydrofuran; hexane / Inert atmosphere; Cooling with acetone-dry ice

3.2: 3 h / Cooling with acetone-dry ice; Inert atmosphere

With N-Bromosuccinimide; n-butyllithium; copper; potassium carbonate; In tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene; hexane; N,N-dimethyl-formamide;

DOI:10.1016/j.orgel.2011.03.015

upstream raw materials:

9-(2-bromophenyl)-9H-carbazole

3-bromo-9-(2-bromophenyl)-9H-carbazole

chloro-diphenylphosphine

1-Bromo-2-iodobenzene

Downstream raw materials:

3-(diphenylphosphoryl)-9-(2-(diphenylphosphoryl)phenyl)-9H-carbazole