[5-bromo-10,20-bis(2,6-didodecyloxyphenyl)porphyrinato]zinc(II)

Base Information

• Chemical Name: [5-bromo-10,20-bis(2,6-didodecyloxyphenyl)porphyrinato]zinc(II)
• CAS No.: 1332509-43-9
• Molecular Formula: C₈₀H₁₁₅BrN₄O₄Zn
• Molecular Weight: 1342.11
• Mol file: 1332509-43-9.mol

Synonyms:[5-bromo-10,20-bis(2,6-didodecyloxyphenyl)porphyrinato]zinc(II)

Chemical Property of [5-bromo-10,20-bis(2,6-didodecyloxyphenyl)porphyrinato]zinc(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [5-bromo-10,20-bis(2,6-didodecyloxyphenyl)porphyrinato]zinc(II)

There total 1 articles about [5-bromo-10,20-bis(2,6-didodecyloxyphenyl)porphyrinato]zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

5-bromo-10,20-bis(2,6-didodecyloxyphenyl)porphyrin + zinc(II) acetate dihydrate (5970-45-6) → [5-bromo-10,20-bis(2,6-didodecyloxyphenyl)porphyrinato]zinc(II) (1332509-43-9)

Guidance literature:

In methanol; dichloromethane;

DOI:10.1039/d1cc03314j

Reference yield: 95.0%

[5-bromo-10,20-bis(2,6-didodecyloxyphenyl)porphyrinato]zinc(II) (1332509-43-9) + tris-iso-propylsilyl acetylene (89343-06-6) → [5,15-bis(2,6-di-dodecyloxyphenyl)-10-(triisopropylsilyl)ethynyl-porphyrinato]zinc(II)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; In tetrahydrofuran; for 4h; Heating; Reflux; Inert atmosphere; Schlenk technique;

DOI:10.1142/S1088424614500308

Reference yield: 53.6%

[5-bromo-10,20-bis(2,6-didodecyloxyphenyl)porphyrinato]zinc(II) (1332509-43-9) + 4-Ethynyl-benzoic acid (10602-00-3) → 5-(4-carboxyphenyl)ethynyl-10,20-bis[2,6-di(dodecyloxy)phenyl]porphinato zinc(II) (1332509-40-6)

Guidance literature:

With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; In tetrahydrofuran; at 40 ℃; for 48h; Inert atmosphere;

DOI:10.1039/c1cc12764k

upstream raw materials:

zinc(II) acetate dihydrate

Downstream raw materials:

5-(4-carboxyphenyl)ethynyl-10,20-bis[2,6-di(dodecyloxy)phenyl]porphinato zinc(II)