2,9-dimethyl-1,10-phenanthroline-bis(triphenyl)phosphine copper(I)tetrafluoroborate

Base Information

Chemical Name:2,9-dimethyl-1,10-phenanthroline-bis(triphenyl)phosphine copper(I)tetrafluoroborate
CAS No.:97567-29-8
Molecular Formula:BF₄*C₅₀H₄₂CuN₂P₂
Molecular Weight:883.195
Hs Code.:

Synonyms:2,9-dimethyl-1,10-phenanthroline-bis(triphenyl)phosphine copper(I)tetrafluoroborate

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Chemical Property of 2,9-dimethyl-1,10-phenanthroline-bis(triphenyl)phosphine copper(I)tetrafluoroborate

Chemical Property:

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Technology Process of 2,9-dimethyl-1,10-phenanthroline-bis(triphenyl)phosphine copper(I)tetrafluoroborate

There total 2 articles about 2,9-dimethyl-1,10-phenanthroline-bis(triphenyl)phosphine copper(I)tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: tetrakis(acetonitrile)copper(I)tetrafluoroborate

: 484-11-7
2.9-dimethyl-1,10-phenanthroline

: 603-35-0
triphenylphosphine

: 97567-29-8
2,9-dimethyl-1,10-phenanthroline-bis(triphenyl)phosphine copper(I)tetrafluoroborate

Guidance literature:: tetrakis(acetonitrile)copper(I)tetrafluoroborate; triphenylphosphine; In dichloromethane; at 20 ℃; for 0.5h;

2.9-dimethyl-1,10-phenanthroline; In dichloromethane; at 20 ℃; for 0.5h;
DOI:10.1016/j.saa.2014.01.019

Reference yield:

: 484-11-7
2.9-dimethyl-1,10-phenanthroline

: copper(II) tetrafluoroborate hydrate

: 97567-29-8
2,9-dimethyl-1,10-phenanthroline-bis(triphenyl)phosphine copper(I)tetrafluoroborate

Guidance literature:: With PPh₃; In diethyl ether; ethanol; one equiv. of Cu(BF4)2*nH2O and 6 equiv. of PPh3 refluxed in EtOH, solid suspended in ether, 1 equiv. of dmp slowly added, mixt. stirred for several h; mixt. cooled, filtered, crystals washed with ether, recrystd. from methanol contg. slight excess of PPh3; elem. anal.;
DOI:10.1021/ja00409a048

Reference yield:

: 97567-29-8
2,9-dimethyl-1,10-phenanthroline-bis(triphenyl)phosphine copper(I)tetrafluoroborate

: 7688-25-7
1,4-di(diphenylphosphino)-butane

: [(2,9-dimethyl-1,10-phenanthroline)Cu(μ-1,4-bis(diphenylphosphino)butane)2Cu(2,6-dimethyl-1,10-phenanthroline)][BF4]2

Guidance literature:: In acetone; stoichiometric amounts reacted for 1 h; washed (ether), dissolved in 1:1 acetone/ethanol and recrystd. at 0°C;
DOI:10.1007/BF01666965