tris(phenyl)(η5-cyclopentadienyl)zirconium(IV) monoetherate

Base Information

• Chemical Name: tris(phenyl)(η5-cyclopentadienyl)zirconium(IV) monoetherate
• CAS No.: 80327-19-1
• Molecular Formula: C₄H₁₀O*C₂₃H₂₀Zr
• Molecular Weight: 461.759
• Mol file: 80327-19-1.mol

Synonyms:tris(phenyl)(η5-cyclopentadienyl)zirconium(IV) monoetherate

Chemical Property of tris(phenyl)(η5-cyclopentadienyl)zirconium(IV) monoetherate

Chemical Property:

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Technology Process of tris(phenyl)(η5-cyclopentadienyl)zirconium(IV) monoetherate

There total 1 articles about tris(phenyl)(η5-cyclopentadienyl)zirconium(IV) monoetherate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

cyclopentadienylzirconium trichloride + phenyllithium (591-51-5) → tris(phenyl)(η5-cyclopentadienyl)zirconium(IV) monoetherate (80327-19-1)

Guidance literature:

With diethyl ether; In diethyl ether; byproducts: lithium chloride; under Ar atm. etheral soln. PhLi added to suspn. CpZrCl3 in ether at -30°C over 30 min, react. mixt. allowed to warm up and stirred at 0°C for 1 h; ether removed in vacuo, residue washed with pentane, dissolved in toluene at 5°C, filtered from LiCl, pentane at -10° added, product filtered and dried in vacuo; elem. anal.;

DOI:10.1021/ic00133a085

upstream raw materials:

phenyllithium