methyl [methyl (7,8,9-tri-O-acetyl-4,5-O-carbonyl-3-deoxy-D-glycero-α-D-galactonon-2-ulopyranosyl)onate]-(2->6)-2,3,4-tri-O-benzyl-β-D-galactopyranoside

Base Information

Chemical Name:methyl [methyl (7,8,9-tri-O-acetyl-4,5-O-carbonyl-3-deoxy-D-glycero-α-D-galactonon-2-ulopyranosyl)onate]-(2->6)-2,3,4-tri-O-benzyl-β-D-galactopyranoside
CAS No.:1227468-46-3
Molecular Formula:C₄₅H₅₂O₁₈
Molecular Weight:880.897
Hs Code.:

methyl [methyl (7,8,9-tri-O-acetyl-4,5-O-carbonyl-3-deoxy-D-glycero-α-D-galactonon-2-ulopyranosyl)onate]-(2->6)-2,3,4-tri-O-benzyl-β-D-galactopyranoside

Synonyms:methyl [methyl (7,8,9-tri-O-acetyl-4,5-O-carbonyl-3-deoxy-D-glycero-α-D-galactonon-2-ulopyranosyl)onate]-(2->6)-2,3,4-tri-O-benzyl-β-D-galactopyranoside

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Chemical Property of methyl [methyl (7,8,9-tri-O-acetyl-4,5-O-carbonyl-3-deoxy-D-glycero-α-D-galactonon-2-ulopyranosyl)onate]-(2->6)-2,3,4-tri-O-benzyl-β-D-galactopyranoside

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Technology Process of methyl [methyl (7,8,9-tri-O-acetyl-4,5-O-carbonyl-3-deoxy-D-glycero-α-D-galactonon-2-ulopyranosyl)onate]-(2->6)-2,3,4-tri-O-benzyl-β-D-galactopyranoside

There total 2 articles about methyl [methyl (7,8,9-tri-O-acetyl-4,5-O-carbonyl-3-deoxy-D-glycero-α-D-galactonon-2-ulopyranosyl)onate]-(2->6)-2,3,4-tri-O-benzyl-β-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 40653-32-5,641635-63-4
methyl 2,3,4-tri-O-benzyl-β-D-galactopyranoside

: 1227468-41-8
methyl (1-adamantanyl 7,8,9-tri-O-acetyl-4,5-O-carbonyl-3-deoxy-2-thio-D-glycero-β-D-galacto-2-nonulopyranosid)onate

: 1227468-46-3
methyl [methyl (7,8,9-tri-O-acetyl-4,5-O-carbonyl-3-deoxy-D-glycero-α-D-galactonon-2-ulopyranosyl)onate]-(2->6)-2,3,4-tri-O-benzyl-β-D-galactopyranoside

Guidance literature:: With N-iodo-succinimide; trifluorormethanesulfonic acid; In dichloromethane; acetonitrile; at -78 ℃; for 1h; stereoselective reaction; Inert atmosphere; Molecular sieve;
DOI:10.1002/anie.200907178

Reference yield:

: 40653-32-5,641635-63-4
methyl 2,3,4-tri-O-benzyl-β-D-galactopyranoside

: 1227468-41-8
methyl (1-adamantanyl 7,8,9-tri-O-acetyl-4,5-O-carbonyl-3-deoxy-2-thio-D-glycero-β-D-galacto-2-nonulopyranosid)onate

: 1227468-46-3
methyl [methyl (7,8,9-tri-O-acetyl-4,5-O-carbonyl-3-deoxy-D-glycero-α-D-galactonon-2-ulopyranosyl)onate]-(2->6)-2,3,4-tri-O-benzyl-β-D-galactopyranoside

: methyl [methyl (7,8,9-tri-O-acetyl-4,5-O-carbonyl-3-deoxy-D-glycero-β-D-galactonon-2-ulopyranosyl)onate]-(2->6)-2,3,4-tri-O-benzyl-β-D-galactopyranoside

Guidance literature:: With 1-benzenesulfinyl piperidine; trifluoromethylsulfonic anhydride; In dichloromethane; acetonitrile; at -78 ℃; optical yield given as %de; stereoselective reaction; Inert atmosphere; Molecular sieve;
DOI:10.1002/anie.200907178

Reference yield: 100.0%

: 1227468-46-3
methyl [methyl (7,8,9-tri-O-acetyl-4,5-O-carbonyl-3-deoxy-D-glycero-α-D-galactonon-2-ulopyranosyl)onate]-(2->6)-2,3,4-tri-O-benzyl-β-D-galactopyranoside

: 1227468-57-6
methyl [methyl (3-deoxy-D-glycero-α-D-galactonon-2-ulopyranosyl)onate]-(2->6)-2,3,4-tri-O-benzyl-β-D-galactopyranoside

Guidance literature:: methyl [methyl (7,8,9-tri-O-acetyl-4,5-O-carbonyl-3-deoxy-D-glycero-α-D-galactonon-2-ulopyranosyl)onate]-(2->6)-2,3,4-tri-O-benzyl-β-D-galactopyranoside; With sodium methylate; In methanol; at 20 ℃; for 0.75h; Inert atmosphere;

In methanol;
DOI:10.1002/anie.200907178