bis(tetraphenylphosphonium) bis(μ-thio)(dichloroferrate(II)dithiotungstate(VI))

Base Information

Chemical Name:bis(tetraphenylphosphonium) bis(μ-thio)(dichloroferrate(II)dithiotungstate(VI))
CAS No.:88548-75-8
Molecular Formula:2C₂₄H₂₀P*Cl₂FeS₄W
Molecular Weight:1117.66
Hs Code.:

Synonyms:bis(tetraphenylphosphonium) bis(μ-thio)(dichloroferrate(II)dithiotungstate(VI))

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Chemical Property of bis(tetraphenylphosphonium) bis(μ-thio)(dichloroferrate(II)dithiotungstate(VI))

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Technology Process of bis(tetraphenylphosphonium) bis(μ-thio)(dichloroferrate(II)dithiotungstate(VI))

There total 3 articles about bis(tetraphenylphosphonium) bis(μ-thio)(dichloroferrate(II)dithiotungstate(VI)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 13862-78-7
ammonium tetrathiotungstate

: 2001-45-8
tetraphenyl phosphonium chloride

: iron(II) chloride

: 88548-75-8
bis(tetraphenylphosphonium) bis(μ-thio)(dichloroferrate(II)dithiotungstate(VI))

Guidance literature:: In N,N-dimethyl-formamide; byproducts: NH4Cl; under N2 atm. to DMF added (NH4)2WS4, FeCl2 and Ph4PCl and soln. stirred for 15 min; NH4Cl filtered, abs. ethanol added to filtrate, Et2O added, crystals filtered, washed with Et2O and dried in vacuo; elem. anal.;

Reference yield: 95.0%

: tetraphenylphosphonium tetrathiotungstate

: 73621-81-5
2(C₆H₅)4P⁽¹⁺⁾*Cl₂WS₂FeS₂FeCl₂^(2-)=((C₆H₅)4P)2[Cl₂WS₂FeS₂FeCl₂]

: 88548-75-8
bis(tetraphenylphosphonium) bis(μ-thio)(dichloroferrate(II)dithiotungstate(VI))

Guidance literature:: In acetonitrile; under N2 atm. to CH3CN added (Ph4P)2(Cl2FeS2WS2FeCl2) and mixt. stirredfor 10 min; mixt. filtered, Et2O added to filtrate, crystals filtered, washed with Et2O and dried in vacuo;

Reference yield:

: iron(II) chloride monohydrate

: tetraphenylphosphonium tetrathiotungstate

: 88548-75-8
bis(tetraphenylphosphonium) bis(μ-thio)(dichloroferrate(II)dithiotungstate(VI))

Guidance literature:: In acetonitrile; N2; a soln. of FeCl3*4H2O in CH3CN was added to a soln. of (PPh4)2(WS4) in CH3CN;
DOI:10.1016/j.ica.2004.07.017