Acetic acid 2-((1R,4S)-6-hydroxy-4-isopropenyl-1-methyl-cyclohex-2-enyl)-1-methyl-ethyl ester

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Chemical Name:Acetic acid 2-((1R,4S)-6-hydroxy-4-isopropenyl-1-methyl-cyclohex-2-enyl)-1-methyl-ethyl ester
CAS No.:119619-13-5
Molecular Formula:C₁₅H₂₄O₃
Molecular Weight:252.354
Hs Code.:

Synonyms:Acetic acid 2-((1R,4S)-6-hydroxy-4-isopropenyl-1-methyl-cyclohex-2-enyl)-1-methyl-ethyl ester

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Chemical Property of Acetic acid 2-((1R,4S)-6-hydroxy-4-isopropenyl-1-methyl-cyclohex-2-enyl)-1-methyl-ethyl ester

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Technology Process of Acetic acid 2-((1R,4S)-6-hydroxy-4-isopropenyl-1-methyl-cyclohex-2-enyl)-1-methyl-ethyl ester

There total 7 articles about Acetic acid 2-((1R,4S)-6-hydroxy-4-isopropenyl-1-methyl-cyclohex-2-enyl)-1-methyl-ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 90056-32-9,90129-48-9
1-<(1S,4R,7R)-7-(Bromomethyl)-4,7-dimethyl-6-oxabicyclo<3.2.1>oct-2-en-4-yl>-2-propanol acetate

: 119619-13-5
Acetic acid 2-((1R,4S)-6-hydroxy-4-isopropenyl-1-methyl-cyclohex-2-enyl)-1-methyl-ethyl ester

Guidance literature:: With copper; ammonium chloride; zinc; In ethanol; for 0.833333h; Heating;
DOI:10.1021/ja00192a035

Reference yield:

: 90056-30-7
((1R,4S,6R)-6-Hydroxy-4-isopropenyl-1-methyl-cyclohex-2-enyl)-acetaldehyde

: 119619-13-5
Acetic acid 2-((1R,4S)-6-hydroxy-4-isopropenyl-1-methyl-cyclohex-2-enyl)-1-methyl-ethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: NBS / acetonitrile / 1 h / 0 °C

2: 91 percent / diethyl ether / 1 h / 0 °C

3: 100 percent / pyridine, 4-(dimethylamino)pyridine / CH₂Cl₂ / 3.5 h / Ambient temperature

4: 100 percent / Zn/Cu, NH₄Cl / aq. ethanol / 0.83 h / Heating

With pyridine; dmap; N-Bromosuccinimide; copper; ammonium chloride; zinc; In diethyl ether; ethanol; dichloromethane; acetonitrile;
DOI:10.1021/ja00192a035

Reference yield:

: 90129-47-8
(4S,5R)-4-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enone

: 119619-13-5
Acetic acid 2-((1R,4S)-6-hydroxy-4-isopropenyl-1-methyl-cyclohex-2-enyl)-1-methyl-ethyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: 1.) mercuric acetate, 2.) acetic acid / 1.) 55-60 deg C, 4 d, 2.) r.t., 3 h

2: 100 percent / LiAlH₄ / diethyl ether / 1.17 h / -78 °C

3: xylene / 36 h / 185 °C

4: NBS / acetonitrile / 1 h / 0 °C

5: 91 percent / diethyl ether / 1 h / 0 °C

6: 100 percent / pyridine, 4-(dimethylamino)pyridine / CH₂Cl₂ / 3.5 h / Ambient temperature

7: 100 percent / Zn/Cu, NH₄Cl / aq. ethanol / 0.83 h / Heating

With pyridine; dmap; N-Bromosuccinimide; lithium aluminium tetrahydride; mercury(II) diacetate; copper; ammonium chloride; acetic acid; zinc; In diethyl ether; ethanol; dichloromethane; acetonitrile; xylene;
DOI:10.1021/ja00192a035