α-deuteriobenzaldehyde tosylhydrazone

Base Information

• Chemical Name: α-deuteriobenzaldehyde tosylhydrazone
• CAS No.: 7318-30-1
• Molecular Formula: C₁₄H₁₄N₂O₂S
• Molecular Weight: 275.335
• Mol file: 7318-30-1.mol

Synonyms:α-deuteriobenzaldehyde tosylhydrazone

Chemical Property of α-deuteriobenzaldehyde tosylhydrazone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of α-deuteriobenzaldehyde tosylhydrazone

There total 3 articles about α-deuteriobenzaldehyde tosylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

Benzaldehyde-d (3592-47-0) + toluene-4-sulfonic acid hydrazide (1576-35-8) → α-deuteriobenzaldehyde tosylhydrazone (7318-30-1)

Guidance literature:

In ethanol; Ambient temperature;

DOI:10.1021/ja00242a034

Reference yield:

benzoic acid methyl ester (93-58-3,5705-52-2,80226-58-0) → α-deuteriobenzaldehyde tosylhydrazone (7318-30-1)

Guidance literature:

Multi-step reaction with 3 steps

1: LiAlD₄ / diethyl ether

2: ceric ammonium nutrate / H₂O

3: 65 percent / ethanol / Ambient temperature

With lithium aluminium deuteride; ammonium cerium(IV) nitrate; In diethyl ether; ethanol; water;

DOI:10.1021/ja00242a034

Reference yield:

1,1-dideuteriophenylmethanol (21175-64-4) → α-deuteriobenzaldehyde tosylhydrazone (7318-30-1)

Guidance literature:

Multi-step reaction with 2 steps

1: ceric ammonium nutrate / H₂O

2: 65 percent / ethanol / Ambient temperature

With ammonium cerium(IV) nitrate; In ethanol; water;

DOI:10.1021/ja00242a034

upstream raw materials:

Benzaldehyde-d

toluene-4-sulfonic acid hydrazide

benzoic acid methyl ester

1,1-dideuteriophenylmethanol

Downstream raw materials:

(Z)-N-benzylideneaniline oxide-d

Refernces