(E)-[(buta-1,3-dienyl)methyl(triphenylmethoxymethyl)methylsilyl]methyl acrylate

Base Information

Chemical Name:(E)-[(buta-1,3-dienyl)methyl(triphenylmethoxymethyl)methylsilyl]methyl acrylate
CAS No.:306965-95-7
Molecular Formula:C₂₉H₃₀O₃Si
Molecular Weight:454.641
Hs Code.:

Synonyms:(E)-[(buta-1,3-dienyl)methyl(triphenylmethoxymethyl)methylsilyl]methyl acrylate

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Chemical Property of (E)-[(buta-1,3-dienyl)methyl(triphenylmethoxymethyl)methylsilyl]methyl acrylate

Chemical Property:

Purity/Quality:

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Technology Process of (E)-[(buta-1,3-dienyl)methyl(triphenylmethoxymethyl)methylsilyl]methyl acrylate

There total 4 articles about (E)-[(buta-1,3-dienyl)methyl(triphenylmethoxymethyl)methylsilyl]methyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (buta-1,3-dienyl)bis(chloromethyl)methylsilane

: 306965-95-7
(E)-[(buta-1,3-dienyl)methyl(triphenylmethoxymethyl)methylsilyl]methyl acrylate

Guidance literature:: Multi-step reaction with 5 steps

1: 88 percent / iodine / benzene / 3.5 h / Heating

2: 80 percent / tetrabutylammonium bromide; titanium oxide / 3 h / 80 - 90 °C

3: 96 percent / LiAlH₄ / diethyl ether / 0.5 h / 20 °C

4: 71 percent / lipase from Candida rugosa / diisopropyl ether / 28 h / -20 °C

5: 97 percent / triethylamine / CH₂Cl₂ / 48 h / 20 °C

With lithium aluminium tetrahydride; titanium oxide; tetrabutylammomium bromide; iodine; triethylamine; lipase from Candida rugosa; In diethyl ether; dichloromethane; di-isopropyl ether; benzene; 1: Isomerization / 2: Acetylation / 3: Reduction / 4: Esterification / 5: Substitution;
DOI:10.1002/1099-0690(200009)2000:17<3039::AID-EJOC3039>3.0.CO;2-X

Reference yield:

: 306966-29-0
(E)-(buta-1,3-dienyl)bis(chloromethyl)methylsilane

: 306965-95-7
(E)-[(buta-1,3-dienyl)methyl(triphenylmethoxymethyl)methylsilyl]methyl acrylate

Guidance literature:: Multi-step reaction with 4 steps

1: 80 percent / tetrabutylammonium bromide; titanium oxide / 3 h / 80 - 90 °C

2: 96 percent / LiAlH₄ / diethyl ether / 0.5 h / 20 °C

3: 71 percent / lipase from Candida rugosa / diisopropyl ether / 28 h / -20 °C

4: 97 percent / triethylamine / CH₂Cl₂ / 48 h / 20 °C

With lithium aluminium tetrahydride; titanium oxide; tetrabutylammomium bromide; triethylamine; lipase from Candida rugosa; In diethyl ether; dichloromethane; di-isopropyl ether; 1: Acetylation / 2: Reduction / 3: Esterification / 4: Substitution;
DOI:10.1002/1099-0690(200009)2000:17<3039::AID-EJOC3039>3.0.CO;2-X

Reference yield:

: 306965-71-9
(E)-(buta-1,3-dienyl)bis(hydroxymethyl)methylsilane

: 306965-95-7
(E)-[(buta-1,3-dienyl)methyl(triphenylmethoxymethyl)methylsilyl]methyl acrylate

Guidance literature:: Multi-step reaction with 2 steps

1: 71 percent / lipase from Candida rugosa / diisopropyl ether / 28 h / -20 °C

2: 97 percent / triethylamine / CH₂Cl₂ / 48 h / 20 °C

With triethylamine; lipase from Candida rugosa; In dichloromethane; di-isopropyl ether; 1: Esterification / 2: Substitution;
DOI:10.1002/1099-0690(200009)2000:17<3039::AID-EJOC3039>3.0.CO;2-X