{rhodium(I)(1,2-bis(diphenylphosphino)ethane)(NBD)} perchlorate

Base Information

• Chemical Name: {rhodium(I)(1,2-bis(diphenylphosphino)ethane)(NBD)} perchlorate
• CAS No.: 32799-34-1
• Molecular Formula: C₃₃H₃₂P₂Rh*ClO₄
• Molecular Weight: 692.921
• Mol file: 32799-34-1.mol

Synonyms:{rhodium(I)(1,2-bis(diphenylphosphino)ethane)(NBD)} perchlorate

Chemical Property of {rhodium(I)(1,2-bis(diphenylphosphino)ethane)(NBD)} perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {rhodium(I)(1,2-bis(diphenylphosphino)ethane)(NBD)} perchlorate

There total 3 articles about {rhodium(I)(1,2-bis(diphenylphosphino)ethane)(NBD)} perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(bicyclo[2.2.1]hepta-2,5-diene)-(2,4-pentanedionato)rhodium (I) → {rhodium(I)(1,2-bis(diphenylphosphino)ethane)(NBD)} perchlorate (32799-34-1)

Guidance literature:

With perchloric acid; 1,2-bis-(diphenylphosphino)ethane; In tetrahydrofuran; react. of the Rh complex with the phosphine in THF in the presence of HClO4 under inert atmosphere according to the method of Schrock, R. R. and Osborn, J. A., J. Amer. Chem. Soc. 93, 2397 (1971);

DOI:10.1016/0021-9517(83)90228-2

Reference yield:

{Rh(NBD)2}ClO4 (60576-58-1) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → {rhodium(I)(1,2-bis(diphenylphosphino)ethane)(NBD)} perchlorate (32799-34-1)

Guidance literature:

With potassium hydroxide; In isopropyl alcohol; under argon, refluxed for 1 h;

DOI:10.1016/S0022-328X(81)80014-9

Reference yield:

(bicyclo[2.2.1]hepta-2,5-diene)-(2,4-pentanedionato)rhodium (I) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → {rhodium(I)(1,2-bis(diphenylphosphino)ethane)(NBD)} perchlorate (32799-34-1)

Guidance literature:

With perchloric acid; by method: R. R. Schrock and J. A. Osborn, J. AM. Chem. Soc., 93 (1971)2397.;

DOI:10.1016/S0022-328X(00)80992-4

upstream raw materials:

{Rh(NBD)2}ClO₄

1,2-bis-(diphenylphosphino)ethane

Downstream raw materials:

[Rh(bis(diphenylphosphanyl)ethane)]ClO₄

Rh(1,2-bis(diphenylphosphino)ethane)(acetone)2(ClO₄)