(1R,2S)-2-[2-(Dimethyl-phenyl-silanyl)-ethyl]-4-((R)-2-hydroxy-1-methyl-ethyl)-5-methylene-cyclohex-3-enol

Base Information

Chemical Name:(1R,2S)-2-[2-(Dimethyl-phenyl-silanyl)-ethyl]-4-((R)-2-hydroxy-1-methyl-ethyl)-5-methylene-cyclohex-3-enol
CAS No.:828915-79-3
Molecular Formula:C₂₀H₃₀O₂Si
Molecular Weight:330.543
Hs Code.:

Synonyms:(1R,2S)-2-[2-(Dimethyl-phenyl-silanyl)-ethyl]-4-((R)-2-hydroxy-1-methyl-ethyl)-5-methylene-cyclohex-3-enol

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Chemical Property of (1R,2S)-2-[2-(Dimethyl-phenyl-silanyl)-ethyl]-4-((R)-2-hydroxy-1-methyl-ethyl)-5-methylene-cyclohex-3-enol

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Technology Process of (1R,2S)-2-[2-(Dimethyl-phenyl-silanyl)-ethyl]-4-((R)-2-hydroxy-1-methyl-ethyl)-5-methylene-cyclohex-3-enol

There total 9 articles about (1R,2S)-2-[2-(Dimethyl-phenyl-silanyl)-ethyl]-4-((R)-2-hydroxy-1-methyl-ethyl)-5-methylene-cyclohex-3-enol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 828915-80-6
[(2-{6-(tert-butyl-dimethyl-silanyloxy)-3-[2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-ethyl]-4-methylene-cyclohex-2-enyl}-ethyl)-dimethyl-silanyl]-benzene

: 828915-79-3
(1R,2S)-2-[2-(Dimethyl-phenyl-silanyl)-ethyl]-4-((R)-2-hydroxy-1-methyl-ethyl)-5-methylene-cyclohex-3-enol

: 828915-81-7
(R)-2-{(3S,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-[2-(dimethyl-phenyl-silanyl)-ethyl]-6-methylene-cyclohex-1-enyl}-propan-1-ol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 ℃;
DOI:10.1002/anie.200460936

Reference yield: 61.0%

: 4776-37-8
(iodomethyl)magnesium chloride

: C₁₀H₁₅LiSi

: 828915-76-0
(1S,2S,6S,8R)-2-Methyl-4,11-dioxa-5-thia-tricyclo[6.2.1.0^1,6]undec-9-ene 5,5-dioxide

: 828915-79-3
(1R,2S)-2-[2-(Dimethyl-phenyl-silanyl)-ethyl]-4-((R)-2-hydroxy-1-methyl-ethyl)-5-methylene-cyclohex-3-enol

Guidance literature:: (1S,2S,6S,8R)-2-Methyl-4,11-dioxa-5-thia-tricyclo[6.2.1.0^1,6]undec-9-ene 5,5-dioxide; With methyllithium; In tetrahydrofuran; at -78 ℃;

C₁₀H₁₅LiSi; In tetrahydrofuran; at -78 - -20 ℃;

(iodomethyl)magnesium chloride; In tetrahydrofuran; at -78 ℃; for 20h;
DOI:10.1002/anie.200460936