6-tert-butyldiphenylsilyl-6,7,12,13-tetrahydro-5H-indeno[2,1-a]pyrrolo[3,4-c]carbazol-5-one

Base Information

• Chemical Name: 6-tert-butyldiphenylsilyl-6,7,12,13-tetrahydro-5H-indeno[2,1-a]pyrrolo[3,4-c]carbazol-5-one
• CAS No.: 251942-48-0
• Molecular Formula: C₃₇H₃₂N₂OSi
• Molecular Weight: 548.759
• Mol file: 251942-48-0.mol

Synonyms:6-tert-butyldiphenylsilyl-6,7,12,13-tetrahydro-5H-indeno[2,1-a]pyrrolo[3,4-c]carbazol-5-one

Chemical Property of 6-tert-butyldiphenylsilyl-6,7,12,13-tetrahydro-5H-indeno[2,1-a]pyrrolo[3,4-c]carbazol-5-one

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 6-tert-butyldiphenylsilyl-6,7,12,13-tetrahydro-5H-indeno[2,1-a]pyrrolo[3,4-c]carbazol-5-one

There total 1 articles about 6-tert-butyldiphenylsilyl-6,7,12,13-tetrahydro-5H-indeno[2,1-a]pyrrolo[3,4-c]carbazol-5-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

tert-butylchlorodiphenylsilane (58479-61-1) + 6H,7H,12H,13H-indeno[2,1-a]pyrrolo[3,4-c]carbazole-5(5H)one (174349-13-4) → 6-tert-butyldiphenylsilyl-6,7,12,13-tetrahydro-5H-indeno[2,1-a]pyrrolo[3,4-c]carbazol-5-one (251942-48-0)

Guidance literature:

With dmap; triethylamine; In N,N-dimethyl-formamide; at 50 ℃; for 35h;

DOI:10.1021/jo0108360

Reference yield: 76.0%

6-tert-butyldiphenylsilyl-6,7,12,13-tetrahydro-5H-indeno[2,1-a]pyrrolo[3,4-c]carbazol-5-one (251942-48-0) + 3-(5,5-dimethyl-1,3-dioxanyl)-propionaldehyde (58697-03-3) → C46H48N2O4Si + C46H48N2O4Si

Guidance literature:

With N-benzyl-trimethylammonium hydroxide; In pyridine; for 2h;

DOI:10.1021/jo0108360

Reference yield:

6-tert-butyldiphenylsilyl-6,7,12,13-tetrahydro-5H-indeno[2,1-a]pyrrolo[3,4-c]carbazol-5-one (251942-48-0) → (9SR,12RS,12aSR)-3,9,10,11,12,12a-hexahydro-2-tert-butyldiphenylsilyl-9,12-epoxyindeno[1,2,3-fg]indolo[3,2,1-kl]pyrrolo[3,4-i][1]benzazocin-1-one

Guidance literature:

Multi-step reaction with 2 steps

1: 13 percent / Triton B / pyridine / 2 h

2: 70 percent / BF₃*Et₂O / CH₂Cl₂ / 0.5 h

With boron trifluoride diethyl etherate; N-benzyl-trimethylammonium hydroxide; In pyridine; dichloromethane;

DOI:10.1021/jo0108360

upstream raw materials:

tert-butylchlorodiphenylsilane

6H,7H,12H,13H-indeno[2,1-a]pyrrolo[3,4-c]carbazole-5(5H)one