1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]propan-2-one

Base Information

Chemical Name:1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]propan-2-one
CAS No.:910488-45-8
Molecular Formula:C₂₈H₄₂O₆
Molecular Weight:474.638
Hs Code.:

Synonyms:1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]propan-2-one

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Chemical Property of 1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]propan-2-one

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Technology Process of 1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]propan-2-one

There total 16 articles about 1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]propan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 910488-44-7
1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]propan-2-ol

: 910488-45-8
1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]propan-2-one

Guidance literature:: With pyridine-SO₃ complex; triethylamine; In dichloromethane; dimethyl sulfoxide; at 0 ℃; for 72h;
DOI:10.1021/ol060812l

Reference yield:

: 910488-36-7
(4S)-6-(benzyloxy)-4-hydroxyhexan-2-one

: 910488-45-8
1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]propan-2-one

Guidance literature:: Multi-step reaction with 12 steps

1: 77 percent / SnCl₄ / CH₂Cl₂ / 1 h / -78 °C

2: 96 percent / PPTS / CH₂Cl₂ / 3 h / 20 °C

3: OsO₄; NaIO₄; H₂O / 2,6-lutidine / dioxane / 3 h / 20 °C

4: 185 mg / diethyl ether / 2 h / -78 °C

5: 89 percent / 2,6-lutidine / CH₂Cl₂ / 3 h / -78 °C

6: OsO₄; NaIO₄; H₂O / 2,6-lutidine / dioxane / 3 h / 20 °C

7: 0.738 g / Ti(S,S)(TADDOL) / diethyl ether / 1 h / -78 °C

8: OsO₄; NaIO₄; H₂O / 2,6-lutidine / dioxane / 3 h / 20 °C

9: 0.752 g / SnCl₄ / CH₂Cl₂ / 1 h / -78 °C

10: 97 percent / PPTS / CH₂Cl₂ / 3 h / 20 °C

11: 92 percent / TBAF / tetrahydrofuran / 16 h / 20 °C

12: 88 percent / SO₃*pyr; Et₃N / CH₂Cl₂; dimethylsulfoxide / 72 h / 0 °C

With 2,6-dimethylpyridine; sodium periodate; osmium(VIII) oxide; pyridine-SO₃ complex; Ti(S,S)(TADDOL); tetrabutyl ammonium fluoride; water; pyridinium p-toluenesulfonate; tin(IV) chloride; triethylamine; 2,6-dimethylpyridine; In tetrahydrofuran; 1,4-dioxane; diethyl ether; dichloromethane; dimethyl sulfoxide;
DOI:10.1021/ol060812l

Reference yield:

: 910488-37-8
(3S,5R)-1-benzyloxy-5-methyloct-7-ene-3,5-diol

: 910488-45-8
1-(6-allyl-2,2-dimethyl-[1,3]dioxan-4-yl)-3-[6-(2-benzyloxyethyl)-2,2,4-trimethyl-[1,3]dioxan-4-yl]propan-2-one

Guidance literature:: Multi-step reaction with 11 steps

1: 96 percent / PPTS / CH₂Cl₂ / 3 h / 20 °C

2: OsO₄; NaIO₄; H₂O / 2,6-lutidine / dioxane / 3 h / 20 °C

3: 185 mg / diethyl ether / 2 h / -78 °C

4: 89 percent / 2,6-lutidine / CH₂Cl₂ / 3 h / -78 °C

5: OsO₄; NaIO₄; H₂O / 2,6-lutidine / dioxane / 3 h / 20 °C

6: 0.738 g / Ti(S,S)(TADDOL) / diethyl ether / 1 h / -78 °C

7: OsO₄; NaIO₄; H₂O / 2,6-lutidine / dioxane / 3 h / 20 °C

8: 0.752 g / SnCl₄ / CH₂Cl₂ / 1 h / -78 °C

9: 97 percent / PPTS / CH₂Cl₂ / 3 h / 20 °C

10: 92 percent / TBAF / tetrahydrofuran / 16 h / 20 °C

11: 88 percent / SO₃*pyr; Et₃N / CH₂Cl₂; dimethylsulfoxide / 72 h / 0 °C

With 2,6-dimethylpyridine; sodium periodate; osmium(VIII) oxide; pyridine-SO₃ complex; Ti(S,S)(TADDOL); tetrabutyl ammonium fluoride; water; pyridinium p-toluenesulfonate; tin(IV) chloride; triethylamine; 2,6-dimethylpyridine; In tetrahydrofuran; 1,4-dioxane; diethyl ether; dichloromethane; dimethyl sulfoxide;
DOI:10.1021/ol060812l