(o-diphenylphosphinophenyl-C(1)P)neopentyl(η5-pentamethylcyclopentadienyl)rhodium(III)

Base Information

• Chemical Name: (o-diphenylphosphinophenyl-C(1)P)neopentyl(η5-pentamethylcyclopentadienyl)rhodium(III)
• CAS No.: 84462-74-8
• Molecular Formula: C₃₃H₄₀PRh
• Molecular Weight: 570.56

Synonyms:(o-diphenylphosphinophenyl-C(1)P)neopentyl(η5-pentamethylcyclopentadienyl)rhodium(III)

Chemical Property of (o-diphenylphosphinophenyl-C(1)P)neopentyl(η5-pentamethylcyclopentadienyl)rhodium(III)

Chemical Property:

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Technology Process of (o-diphenylphosphinophenyl-C(1)P)neopentyl(η5-pentamethylcyclopentadienyl)rhodium(III)

There total 2 articles about (o-diphenylphosphinophenyl-C(1)P)neopentyl(η5-pentamethylcyclopentadienyl)rhodium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 12.0%

dichloro(η5-pentamethylcyclopentadienyl)(triphenylphosphine)rhodium(III) + neopentyl lithium (7412-67-1) → (η5-pentamethylcyclopentadienyl)Rh(η2-ethylene)(PPh3) + (o-diphenylphosphinophenyl-C(1)P)neopentyl(η5-pentamethylcyclopentadienyl)rhodium(III) (84462-74-8) + (2,2-dimethylpropane-1,3-diyl)(η5-pentamethylcyclopentadienyl)(triphenylphosphine)rhodium(III)

Guidance literature:

In diethyl ether; Rh-complex was reacted with ligand in Et2O; extd. with pentane, sepd. by column chromy. on alunima, crystd. from pentane;

DOI:10.1039/c39820000945

Reference yield:

dichloro(η5-pentamethylcyclopentadienyl)(triphenylphosphine)rhodium(III) + neopentyl lithium (7412-67-1) → (o-diphenylphosphinophenyl-C(1)P)neopentyl(η5-pentamethylcyclopentadienyl)rhodium(III) (84462-74-8) + (2,2-dimethylpropane-1,3-diyl)(η5-pentamethylcyclopentadienyl)(triphenylphosphine)rhodium(III)

Guidance literature:

In pentane; (N2 or Ar); to a soln. of Rh-complex added a soln. of Li-compound at -10°C; stirred at 0°C for 3 h; evapd.; extracted with pentane; concentrated; chromy.; evapd.; crystd. from pentane at -30°C;

DOI:10.1039/DT9860000803

upstream raw materials:

neopentyl lithium

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