8-azidooctyl 2,3-di-O-benzyl-5-O-[2-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl]-β-D-arabinofuranoside

Base Information

• Chemical Name: 8-azidooctyl 2,3-di-O-benzyl-5-O-[2-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl]-β-D-arabinofuranoside
• CAS No.: 593283-99-9
• Molecular Formula: C₈₁H₉₃N₃O₁₅
• Molecular Weight: 1348.64
• Mol file: 593283-99-9.mol

Synonyms:8-azidooctyl 2,3-di-O-benzyl-5-O-[2-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl]-β-D-arabinofuranoside

Chemical Property of 8-azidooctyl 2,3-di-O-benzyl-5-O-[2-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl]-β-D-arabinofuranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 8-azidooctyl 2,3-di-O-benzyl-5-O-[2-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl]-β-D-arabinofuranoside

There total 1 articles about 8-azidooctyl 2,3-di-O-benzyl-5-O-[2-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl]-β-D-arabinofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

8-azidooctyl 2,3-di-O-benzyl-5-O-[2-O-(2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl]-β-D-arabinofuranoside → 8-azidooctyl 2,3-di-O-benzyl-5-O-[2-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl]-β-D-arabinofuranoside (593283-99-9)

Guidance literature:

With methanol; sodium methylate; In dichloromethane; at 20 ℃; for 4h;

DOI:10.1081/CAR-120021696

Reference yield: 82.0%

8-azidooctyl 2,3-di-O-benzyl-5-O-[2-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl]-β-D-arabinofuranoside (593283-99-9) + S-ethyl 2,3,4,6-tetra-O-acetyl-1-deoxy-1-thio-α-D-mannopyranoside (32934-24-0,41670-79-5,52645-73-5,55722-49-1,79389-52-9,99031-86-4,125354-48-5,126187-25-5) → 8-azidooctyl 5-O-{3,4,6-tri-O-benzyl-2-O-[3,4,6-tri-O-benzyl-2-O-(α-D-mannopyranosyl)-α-D-mannopyranosyl]-α-D-mannopyranosyl}-2,3-di-O-benzyl-β-D-arabinofuranoside (638188-78-0)

Guidance literature:

8-azidooctyl 2,3-di-O-benzyl-5-O-[2-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl]-β-D-arabinofuranoside; S-ethyl 2,3,4,6-tetra-O-acetyl-1-deoxy-1-thio-α-D-mannopyranoside; With N-iodo-succinimide; 4 A molecular sieve; silver trifluoromethanesulfonate; In dichloromethane; at 0 ℃; for 1h;

With sodium methylate; In methanol; for 4h;

DOI:10.1081/CAR-120025322

Reference yield:

8-azidooctyl 2,3-di-O-benzyl-5-O-[2-O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-3,4,6-tri-O-benzyl-α-D-mannopyranosyl]-β-D-arabinofuranoside (593283-99-9) + S-ethyl 2,3,4,6-tetra-O-acetyl-1-deoxy-1-thio-α-D-mannopyranoside (32934-24-0,41670-79-5,52645-73-5,55722-49-1,79389-52-9,99031-86-4,125354-48-5,126187-25-5) → C95H111N3O24

Guidance literature:

With N-iodo-succinimide; silver trifluoromethanesulfonate; In dichloromethane; at 0 ℃; for 1h;

DOI:10.1081/CAR-120021696

Downstream raw materials:

8-azidooctyl 5-O-{3,4,6-tri-O-benzyl-2-O-[3,4,6-tri-O-benzyl-2-O-(α-D-mannopyranosyl)-α-D-mannopyranosyl]-α-D-mannopyranosyl}-2,3-di-O-benzyl-β-D-arabinofuranoside