TiCl(N(C(CD₃)2CH₃)(3,5-C₆H₃Me₂))

Base Information

• Chemical Name: TiCl(N(C(CD₃)2CH₃)(3,5-C₆H₃Me₂))
• CAS No.: 156670-82-5
• Molecular Formula: C₃₆H₅₄ClN₃Ti
• Molecular Weight: 630.035
• Mol file: 156670-82-5.mol

Synonyms:TiCl(N(C(CD₃)2CH₃)(3,5-C₆H₃Me₂))

Chemical Property of TiCl(N(C(CD₃)2CH₃)(3,5-C₆H₃Me₂))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of TiCl(N(C(CD₃)2CH₃)(3,5-C₆H₃Me₂))

There total 2 articles about TiCl(N(C(CD₃)2CH₃)(3,5-C₆H₃Me₂)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.9%

tetrachloro(1,2-dimethoxyethane-O,O')tungsten(IV) (146733-16-6) + Ti(N(C(CD3)2CH3)(3,5-C6H3Me2)) → TiCl(N(C(CD3)2CH3)(3,5-C6H3Me2)) (156670-82-5) + mer-trichlorotris(tetrahydrofuran)tungsten(III) (211572-89-3)

Guidance literature:

In tetrahydrofuran; byproducts: DME; N2-atmosphere; dropwise addn. of Ti-complex to equimolar amt. of W-complex, stirring for 10 min; crystn. (-35°C, 5 h), decantation, washing (-35°C, THF, pentane), drying (vac., 28°C); elem. anal.;

DOI:10.1016/S0020-1693(97)06157-4

Reference yield: 62.0%

tetrachlorobis(tetrahydrofuran)titanium(IV) (31011-57-1,112925-19-6,112925-18-5) + Li(1+)*N(C(C(2)H3)2CH3)(C6H3(CH3)2)(1-)*(C2H5)2O=Li(N(C(C(2)H3)2CH3)(C6H3(CH3)2))*(C2H5)2O (160544-65-0) → TiCl(N(C(CD3)2CH3)(3,5-C6H3Me2)) (156670-82-5)

Guidance literature:

In hexane; byproducts: LiCl; under inert conditions; addn. of the Ti-complex to the Li-compd. in hexane, mixt. stirred (30°C, 48 h); orange-brown react. mixt. filtered (removal of LiCl), evapn. (vac.), recrystn. from hexane (3 crops); elem. anal.;

DOI:10.1021/om00019a057

Reference yield: 73.0%

TiCl(N(C(CD3)2CH3)(3,5-C6H3Me2)) (156670-82-5) → Ti(N(C(CD3)2CH3)(3,5-C6H3Me2))

Guidance literature:

With sodium amalgam; In benzene; stirring (28°C, 60 h); filtn. (Celite), evapn., recrystn. (pentane, -35°C); elem. anal.;

upstream raw materials:

tetrachlorobis(tetrahydrofuran)titanium(IV)

Li⁽¹⁺⁾*N(C(C⁽²⁾H₃)2CH₃)(C₆H₃(CH₃)2)^(1-)*(C₂H₅)2O=Li(N(C(C⁽²⁾H₃)2CH₃)(C₆H₃(CH₃)2))*(C₂H₅)2O

tetrachloro(1,2-dimethoxyethane-O,O')tungsten(IV)

Refernces

• 1、 Johnson, Adam R.,Wanandi, Paulus W.,Cummins, Christopher C.,Davis, William M.. "Cleavage of titanium dimethylamides with methyl iodide". . p. 2907 - 2909. Retrieved 2008/10/08.