cis-[PtCl(2-(diphenylphosphinoamino)pyridine-P,N)(PMe₃)]Cl

Base Information

• Chemical Name: cis-[PtCl(2-(diphenylphosphinoamino)pyridine-P,N)(PMe₃)]Cl
• CAS No.: 300772-90-1
• Molecular Formula: C₂₀H₂₄ClN₂P₂Pt*Cl
• Molecular Weight: 620.357
• Mol file: 300772-90-1.mol

Synonyms:cis-[PtCl(2-(diphenylphosphinoamino)pyridine-P,N)(PMe₃)]Cl

Chemical Property of cis-[PtCl(2-(diphenylphosphinoamino)pyridine-P,N)(PMe₃)]Cl

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of cis-[PtCl(2-(diphenylphosphinoamino)pyridine-P,N)(PMe₃)]Cl

There total 1 articles about cis-[PtCl(2-(diphenylphosphinoamino)pyridine-P,N)(PMe₃)]Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

cis-dichlorobis(trimethylphosphine)platinum(II) (19471-47-7,15630-86-1,21545-76-6) + 2-((diphenylphosphino)amido)pyridine (29938-19-0) → cis-[PtCl(2-(diphenylphosphinoamino)pyridine-P,N)(PMe3)]Cl (300772-90-1)

Guidance literature:

In dichloromethane; byproducts: P(CH3)3; (N2); solid ligand added to stirred suspn. of Pt complex in CH2Cl2, stirred for 10 min; pptd. (Et2O), filtered off, recrystd. (CH2Cl2/Et2O), dried (vac.); elem. anal.;

DOI:10.1039/b003294h

Reference yield: 87.0%

cis-[PtCl(2-(diphenylphosphinoamino)pyridine-P,N)(PMe3)]Cl (300772-90-1) → cis-[PtCl(2-(diphenylphosphinoamino)pyridinato-P,N)(PMe3)] (300772-92-3)

Guidance literature:

With tBuOK; In methanol; (N2); solid tBuOK (stoich. amount) added to stirred soln. of Pt complexin MeOH; drops of H2O added, ppt. filtered off, washed (distd. H2O, ice-cold MeOH), dried (P2O5, vac.); elem. anal.;

DOI:10.1039/b003294h

upstream raw materials:

cis-dichlorobis(trimethylphosphine)platinum(II)

2-((diphenylphosphino)amido)pyridine

Downstream raw materials:

cis-[PtCl(2-(diphenylphosphinoamino)pyridinato-P,N)(PMe₃)]