Technology Process of [[1-(2-furyl)ethenyl]oxy]tri-isopropylsilane
There total 1 articles about [[1-(2-furyl)ethenyl]oxy]tri-isopropylsilane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
N-ethyl-N,N-diisopropylamine;
In
dichloromethane;
at 0 - 20 ℃;
- Guidance literature:
-
Multi-step reaction with 2 steps
1: NCS / tetrahydrofuran / 1 h / -10 °C
2: 67 percent / aqueous HF / acetonitrile / 2 h
With
N-chloro-succinimide; hydrogen fluoride;
In
tetrahydrofuran; acetonitrile;
DOI:10.1016/j.tetasy.2006.07.017
- Guidance literature:
-
Multi-step reaction with 5 steps
1: NCS / tetrahydrofuran / 1 h / -10 °C
2: 67 percent / aqueous HF / acetonitrile / 2 h
3: 77 percent / HCOOH; Et3N / [RuCl2(η6-p-cymene)]2; (1S,2S)-N-p-toluenesulfonyl-1,2-diphenylethylenediamine / dimethylformamide / 1.5 h / 20 °C
4: 65 percent / Et3N / CH2Cl2 / 20 °C
5: 93 percent / KO-t-Bu / tetrahydrofuran / 0.25 h / 20 °C
With
N-chloro-succinimide; formic acid; hydrogen fluoride; potassium tert-butylate; triethylamine;
[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; N-[(1S,2S)-2-amino-1,2-diphenylethyl]-4-methylbenzenesulfonamide;
In
tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; acetonitrile;
3: Noyori asymmetric transfer hydrogenation;
DOI:10.1016/j.tetasy.2006.07.017
