Technology Process of [(μ-SCH2)2N(C6H4CO2Me-p)]Fe2(CO)6
There total 1 articles about [(μ-SCH2)2N(C6H4CO2Me-p)]Fe2(CO)6 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
(C2H5)3BHLi;
In
tetrahydrofuran;
(N2); using Schlenk techniques; cooling of soln. of S2Fe2(CO)6 in THF to-78°C; addn. of soln. of Et3BHLi in THF; addn. of (ClCH2)2NC6H4C O2Me; warming to room temp., stirring at this temp. for 8 h; filtration, evapn. of filtrate to dryness; TLC; using CH2Cl2/petroleum ether (1:5) as eluant; elem. anal.;
- Guidance literature:
-
With
(CH3)3NO*2H2O;
In
acetonitrile;
(N2); using Schlenk techniques; addn. of Me3NO*2H2O (1 equiv.) to soln. of Fe2(CO)6(μ-SCH2)(NC6H4CO2Me); stirring at room temp. for 20 min; addn. of Ph3P; stirring at this temp. for 3 h; removal of volatiles under vac., TLC using CH2Cl2/petroleum ether (v/v=1/2) as eluent; elem. anal.;
DOI:10.1021/om700956e
- Guidance literature:
-
With
Me3NO*2H2O;
In
dichloromethane; acetonitrile;
(N2); std. Schlenk technique; soln. of Me3NO*2H2O (1 equiv.) in MeCN wasadded to soln. of Fe complex in CH2Cl2; stirred at room temp. for 20 mi n; soln. of P ligand (1 equiv.) in CH2Cl2 was added; stirred for 1 h; evapd. (vac.); chromd. (silica gel plates, acetone/petroleum ether, 1/3); elem. anal.;
DOI:10.1021/om300418z
