3-vinyloxymethyl-2,2,5,5-tetramethyl-2,5-dihydro-1H-pyrrol-1-yloxy radical

Base Information

Chemical Name:3-vinyloxymethyl-2,2,5,5-tetramethyl-2,5-dihydro-1H-pyrrol-1-yloxy radical
CAS No.:160252-72-2
Molecular Formula:C₁₁H₁₈NO₂
Molecular Weight:196.269
Hs Code.:

Synonyms:3-vinyloxymethyl-2,2,5,5-tetramethyl-2,5-dihydro-1H-pyrrol-1-yloxy radical

Suppliers and Price of 3-vinyloxymethyl-2,2,5,5-tetramethyl-2,5-dihydro-1H-pyrrol-1-yloxy radical

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-vinyloxymethyl-2,2,5,5-tetramethyl-2,5-dihydro-1H-pyrrol-1-yloxy radical

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-vinyloxymethyl-2,2,5,5-tetramethyl-2,5-dihydro-1H-pyrrol-1-yloxy radical

There total 1 articles about 3-vinyloxymethyl-2,2,5,5-tetramethyl-2,5-dihydro-1H-pyrrol-1-yloxy radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 55738-75-5
(2,5-dihydro-2,2,5,5-tetramethyl-1-oxyl-1H-pyrrol-3-yl)methanol

: 109-92-2,25104-37-4
ethyl vinyl ether

: 160252-72-2
3-vinyloxymethyl-2,2,5,5-tetramethyl-2,5-dihydro-1H-pyrrol-1-yloxy radical

Guidance literature:: With mercury(II) diacetate; for 16h; Heating;
DOI:10.1055/s-1994-25641

Reference yield:

: 160252-72-2
3-vinyloxymethyl-2,2,5,5-tetramethyl-2,5-dihydro-1H-pyrrol-1-yloxy radical

: 3-<(4-azido-N-phthalimido)ethyl>-4-methanethiosulfonylmethyl-2,5-dihydro-2,2,5,5-tetramethyl-1H-pyrrol-1-yloxy radical

Guidance literature:: Multi-step reaction with 9 steps

1: 32 percent / xylene / 20 h / Heating

2: 85 percent / NaBH₄ / ethanol / 0.5 h / 40 °C

3: Et₃N / CH₂Cl₂ / 1 h / 0 °C

4: LiBr / acetone / 1 h / Heating

5: 35 percent / K₂CO₃, KOH, 18-crown-6 / dioxane / 18 h / Heating

6: 1.) ascorbinic acid, 2.) Et₃N / 1.) dioxane, H₂O, 40 deg C, 15 min, 2.) CHCl₃, 0 deg C, 1 h

7: 56 percent / NBS, benzoylperoxide / CCl₄ / 14 h / Heating; var. reag.: 1,3-dibromo-5,5-dimethylhydantoine

8: 28 percent / NaOMe / methanol; tetrahydrofuran / 0.5 h / Ambient temperature; spontaneous oxidation

9: 66 percent / dioxane; H₂O / 0.5 h / Heating

With potassium hydroxide; sodium tetrahydroborate; N-Bromosuccinimide; Perbenzoic acid; 18-crown-6 ether; sodium methylate; potassium carbonate; triethylamine; lithium bromide; ascorbic acid; In tetrahydrofuran; 1,4-dioxane; methanol; tetrachloromethane; ethanol; dichloromethane; water; acetone; xylene;
DOI:10.1055/s-1994-25641