1-D-6-O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-galactopyranosyl)-3,4,5-tri-O-benzyl-2-O-methyl-myo-inositol 1-(acetoxymethyl octadecyl phosphate)

Base Information

Chemical Name:1-D-6-O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-galactopyranosyl)-3,4,5-tri-O-benzyl-2-O-methyl-myo-inositol 1-(acetoxymethyl octadecyl phosphate)
CAS No.:869192-43-8
Molecular Formula:C₇₆H₁₀₀N₃O₁₅P
Molecular Weight:1326.61
Hs Code.:

Synonyms:1-D-6-O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-galactopyranosyl)-3,4,5-tri-O-benzyl-2-O-methyl-myo-inositol 1-(acetoxymethyl octadecyl phosphate)

Suppliers and Price of 1-D-6-O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-galactopyranosyl)-3,4,5-tri-O-benzyl-2-O-methyl-myo-inositol 1-(acetoxymethyl octadecyl phosphate)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-D-6-O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-galactopyranosyl)-3,4,5-tri-O-benzyl-2-O-methyl-myo-inositol 1-(acetoxymethyl octadecyl phosphate)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-D-6-O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-galactopyranosyl)-3,4,5-tri-O-benzyl-2-O-methyl-myo-inositol 1-(acetoxymethyl octadecyl phosphate)

There total 5 articles about 1-D-6-O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-galactopyranosyl)-3,4,5-tri-O-benzyl-2-O-methyl-myo-inositol 1-(acetoxymethyl octadecyl phosphate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: tetraethylammonium 1-D-6-O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-galactopyranosyl)-3,4,5-tri-O-benzyl-2-O-methyl-myo-inositol 1-(octadecyl phosphate)

: 590-97-6
acetoxymethyl bromide

: 869192-43-8
1-D-6-O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-galactopyranosyl)-3,4,5-tri-O-benzyl-2-O-methyl-myo-inositol 1-(acetoxymethyl octadecyl phosphate)

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; at 20 ℃;
DOI:10.1016/j.tetlet.2005.08.112

Reference yield:

: 869192-40-5
1-D-6-O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-galactopyranosyl)-3,4,5-tri-O-benzyl-2-O-methyl-myo-inositol

: 869192-43-8
1-D-6-O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-galactopyranosyl)-3,4,5-tri-O-benzyl-2-O-methyl-myo-inositol 1-(acetoxymethyl octadecyl phosphate)

Guidance literature:: Multi-step reaction with 2 steps

1.1: pivaloyl chloride / pyridine / 1 h / 20 °C

1.2: 43 percent / iodine / pyridine; H₂O / 0.75 h / 20 °C

2.1: 65 percent / DIEA / tetrahydrofuran / 20 °C

With pivaloyl chloride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; pyridine;
DOI:10.1016/j.tetlet.2005.08.112

Reference yield:

: 869192-39-2
(3R,4R,5R,6R)-3-Azido-4,5-bis-benzyloxy-6-benzyloxymethyl-2-[(1S,2S,3R,4S,5R,6R)-2,3,4-tris-benzyloxy-5-methoxy-6-(4-methoxy-benzyloxy)-cyclohexyloxy]-tetrahydro-pyran

: 869192-43-8
1-D-6-O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-galactopyranosyl)-3,4,5-tri-O-benzyl-2-O-methyl-myo-inositol 1-(acetoxymethyl octadecyl phosphate)

Guidance literature:: Multi-step reaction with 3 steps

1.1: 34 percent / TFA / CH₂Cl₂ / 1 h / 20 °C

2.1: pivaloyl chloride / pyridine / 1 h / 20 °C

2.2: 43 percent / iodine / pyridine; H₂O / 0.75 h / 20 °C

3.1: 65 percent / DIEA / tetrahydrofuran / 20 °C

With pivaloyl chloride; N-ethyl-N,N-diisopropylamine; trifluoroacetic acid; In tetrahydrofuran; pyridine; dichloromethane;
DOI:10.1016/j.tetlet.2005.08.112