Tetrakis(1H-imidazol-1-yl)copper(2+) dinitrate

Base Information

• Chemical Name: Tetrakis(1H-imidazol-1-yl)copper(2+) dinitrate
• CAS No.: 33790-63-5
• Molecular Formula: C₁₂H₁₆CuN₁₀O₆
• Molecular Weight: 459.868
• Mol file: 33790-63-5.mol

Synonyms:(Im)4Cu(II) dinitrate;tetrakis(1H-imidazol-1-yl)copper(2+) dinitrate;tetrakis(imidazolyl)copper(II) dinitrate

Chemical Property of Tetrakis(1H-imidazol-1-yl)copper(2+) dinitrate

Chemical Property:

• Boiling Point: 187oC at 760 mmHg
• Flash Point: 87.5oC
• PSA: 252.48000
• LogP: 2.20450
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 0
• Exact Mass: 459.055025
• Heavy Atom Count: 29
• Complexity: 74.9

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CNN=C1.C1=CN=CN1.C1=CN=CN1.C1=CN=CN1.[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Cu+2]

Technology Process of Tetrakis(1H-imidazol-1-yl)copper(2+) dinitrate

There total 4 articles about Tetrakis(1H-imidazol-1-yl)copper(2+) dinitrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

1H-imidazole (288-32-4) + copper(II) nitrate trihydrate → tetrakis(imidazole)dinitrato copper(II) (33790-63-5)

Guidance literature:

In ethanol; at 20 ℃; for 72h;

DOI:10.1021/acs.inorgchem.6b00814

Reference yield: 85.0%

copper(II) nitrate trihydrate + 1,1'-carbonyldiimidazole (530-62-1) → trans-Cu(NO3)2(imidazole)4 (12318-66-0,33011-78-8,33790-63-5,52984-47-1)

Guidance literature:

In ethanol; (under aerobic conditions); EtOH soln. of Cu(NO3)2*3H2O treated with ligand, stirred for 30 min; filtered, filtrate layered with n-hexane, slowly mixed, filtered, washedwith cold Et2O, dried in vacuo over silica gel; elem. anal.;

DOI:10.1039/b900716d

Reference yield:

1H-imidazole (288-32-4) + copper(II) nitrate → Cu(C3N2H4)4(NO3)2 (12318-66-0,33011-78-8,33790-63-5,52984-47-1)

Guidance literature:

In ethanol; the product was washed with cold ethanol;

DOI:10.1016/0022-2860(80)80161-X

upstream raw materials:

1H-imidazole

1,1'-carbonyldiimidazole

Refernces

• 1、 Stamatatos, Theocharis C.,Perlepes, Spyros P.,Raptopoulou, Catherine P.,Terzis, Aris,Patrickios, Costas S.,Tasiopoulos, Anastasios J.,Boudalis, Athanassios K.. "Alcoholysis/hydrolysis of 1,1′-carbonyldiimidazole as a means of preparing unprecedented, imidazole-containing one-dimensional coordination polymers of copper(II)". . p. 3354 - 3362. Retrieved 2009/08/08.