methyl (2,4,6-tri-O-acetyl-3-azido-3-deoxy-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside

Base Information

• Chemical Name: methyl (2,4,6-tri-O-acetyl-3-azido-3-deoxy-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside
• CAS No.: 593281-67-5
• Molecular Formula: C₃₃H₃₇N₃O₁₄
• Molecular Weight: 699.668

Synonyms:methyl (2,4,6-tri-O-acetyl-3-azido-3-deoxy-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside

Chemical Property of methyl (2,4,6-tri-O-acetyl-3-azido-3-deoxy-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl (2,4,6-tri-O-acetyl-3-azido-3-deoxy-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside

There total 2 articles about methyl (2,4,6-tri-O-acetyl-3-azido-3-deoxy-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

3-azido-2,4,6-tri-O-acetyl-3-deoxy-α-D-glucopyranosyl trichloroacetimidate (485809-82-3) + methyl 2-O-benzoyl-4,6-di-O-benzylidene-α-D-glucopyranoside (28642-64-0,35823-97-3,38992-99-3,51591-23-2,55169-75-0,56253-26-0,72659-78-0,80041-30-1,80299-59-8,86420-70-4,86420-72-6,91685-06-2,99265-94-8,109010-33-5,118246-05-2,126255-07-0) → methyl (2,4,6-tri-O-acetyl-3-azido-3-deoxy-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside (593281-67-5)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; In dichloromethane; at 20 ℃; for 0.416667h;

DOI:10.1002/chem.200304733

Reference yield:

1,2,6-tri-O-acetyl-3-azido-3-deoxy-D-glucopyranose → methyl (2,4,6-tri-O-acetyl-3-azido-3-deoxy-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside (593281-67-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 81 percent / DBU / CH₂Cl₂ / 2 h / 0 - 20 °C

2: 65 percent / molecular sieves 4 Angstroem; TMSOTf / CH₂Cl₂ / 0.42 h / 20 °C

With trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane;

DOI:10.1002/chem.200304733

Reference yield:

methyl (2,4,6-tri-O-acetyl-3-azido-3-deoxy-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside (593281-67-5) → (2S,3R,4S,5S,6R)-4-Azido-2-((2R,4aR,6S,7R,8R,8aR)-7-hydroxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yloxy)-6-hydroxymethyl-tetrahydro-pyran-3,5-diol

Guidance literature:

With sodium methylate; In methanol; at 0 - 20 ℃; for 2h;

DOI:10.1002/chem.200304733

upstream raw materials:

3-azido-2,4,6-tri-O-acetyl-3-deoxy-α-D-glucopyranosyl trichloroacetimidate

methyl 2-O-benzoyl-4,6-di-O-benzylidene-α-D-glucopyranoside

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 593281-67-5 methyl (2,4,6-tri-O-acetyl-3-azido-3-deoxy-β-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside

Send

Send

Metric Ton KG G Pound L ML

Send

Send