1,5-diisopropylcyclohexa-1,4-diene

Base Information

• Chemical Name: 1,5-diisopropylcyclohexa-1,4-diene
• CAS No.: 1291093-63-4
• Molecular Formula: C₁₂H₂₀
• Molecular Weight: 164.291
• Mol file: 1291093-63-4.mol

Synonyms:1,5-diisopropylcyclohexa-1,4-diene

Chemical Property of 1,5-diisopropylcyclohexa-1,4-diene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,5-diisopropylcyclohexa-1,4-diene

There total 1 articles about 1,5-diisopropylcyclohexa-1,4-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

1,3-diisopropylbenzene (99-62-7) → 1,5-diisopropylcyclohexa-1,4-diene (1291093-63-4)

Guidance literature:

With N,N'-Dimethylurea; tris(pyrrolidino)phosphine oxide; lithium bromide; In tetrahydrofuran; at 20 ℃; Electrochemical reaction;

DOI:10.1126/science.aav5606

Reference yield:

1,5-diisopropylcyclohexa-1,4-diene (1291093-63-4) → 1,3-diisopropylcyclohexane (7045-70-7) + 1,3-diisopropylcyclohexane

Guidance literature:

With hydrogen; In dichloromethane; for 18h; under 15001.5 Torr; optical yield given as %ee; enantioselective reaction;

DOI:10.1055/s-0031-1289569

Reference yield:

1,5-diisopropylcyclohexa-1,4-diene (1291093-63-4) → 1,3-diisopropylcyclohexane (7045-70-7) + C12H24

Guidance literature:

With C₈H₁₂*C₂₆H₂₅N₂P*C₃₂H₁₂BF₂₄^(1-)*Ir⁽¹⁺⁾; hydrogen; In dichloromethane; for 18h; under 15001.5 Torr; optical yield given as %de; stereoselective reaction;

DOI:10.1039/c0cc05619g

upstream raw materials:

1,3-diisopropylbenzene

Downstream raw materials:

1,3-diisopropylcyclohexane

Refernces

• 1、 Peters, Byron K.,Rodriguez, Kevin X.,Reisberg, Solomon H.,Beil, Sebastian B.,Kawamata, Yu,Baran, Phil S.,Hickey, David P.,Klunder, Kevin,Gorey, Timothy J.,Anderson, Scott L.,Minteer, Shelley D.,Collins, Michael,Starr, Jeremy,Chen, Longrui,Udyavara, Sagar,Neurock, Matthew. "Scalable and safe synthetic organic electroreduction inspired by Li-ion battery chemistry". . p. 838 - 845. Retrieved 2019/04/30.