C₅H₅Re(NO)CHCH₂C₆H₅C₆H₅P(C₆H₅)3

Base Information

Chemical Name:C₅H₅Re(NO)CHCH₂C₆H₅C₆H₅P(C₆H₅)3
CAS No.:82399-56-2
Molecular Formula:C₃₇H₃₃NOPRe
Molecular Weight:724.856
Hs Code.:

C<sub>5</sub>H<sub>5</sub>Re(NO)CHCH<sub>2</sub>C<sub>6</sub>H<sub>5</sub>C<sub>6</sub>H<sub>5</sub>P(C<sub>6</sub>H<sub>5</sub>)3

Synonyms:C₅H₅Re(NO)CHCH₂C₆H₅C₆H₅P(C₆H₅)3

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Chemical Property of C₅H₅Re(NO)CHCH₂C₆H₅C₆H₅P(C₆H₅)3

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Technology Process of C₅H₅Re(NO)CHCH₂C₆H₅C₆H₅P(C₆H₅)3

There total 2 articles about C₅H₅Re(NO)CHCH₂C₆H₅C₆H₅P(C₆H₅)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 74561-64-1
C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

: 6921-34-2
benzylmagnesium chloride

: 82399-56-2
C₅H₅Re(NO)CHCH₂C₆H₅C₆H₅P(C₆H₅)3

Guidance literature:: In tetrahydrofuran; dichloromethane; Re-complex was dissolved in CH2Cl2 under N2, cooled to -78°C, ligand in THF was added dropwise, after 20 min at -78°C soln. was allowed to warm to room temp.; solvent was removed under vac., residue extd. with benzene, filtered through silica gel, benzene was removed by rotary evaporator, chromd. on silica gel column (CH2Cl2/hexane), collected, solvent was removed in vac.;
DOI:10.1021/ja00382a021

Reference yield:

: 74540-78-6
C₅H₅Re(NO)CHC₆H₅P(C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Re(C₅H₅)NOP(C₆H₅)3CHC₆H₅PF₆

: 6921-34-2
benzylmagnesium chloride

: 82399-56-2
C₅H₅Re(NO)CHCH₂C₆H₅C₆H₅P(C₆H₅)3

: 82374-41-2
C₅H₅Re(NO)CH(CH₂C₆H₅)C₆H₅P(C₆H₅)3

Guidance literature:: In tetrahydrofuran; to -78°C soln. of Re-complex was added dropwise CH3Li in THF, after 15 min at -78°C mixt. was allowed to warm to room temp. underN2; residue extd. with benzene, filtered through silica gel, solvent was removed, residue chromd. on silica gel column (CH2Cl2/hexane), collected, solvent was removed; detd. by NMR;
DOI:10.1021/ja00382a021