(μ-1,3-dicyanoadamantane)bis(pentaammineruthenium(II)) perchlorate

Base Information

• Chemical Name: (μ-1,3-dicyanoadamantane)bis(pentaammineruthenium(II)) perchlorate
• CAS No.: 83664-85-1
• Molecular Formula: C₁₂H₄₄N₁₂Ru₂*4ClO₄
• Molecular Weight: 956.504
• Mol file: 83664-85-1.mol

Synonyms:(μ-1,3-dicyanoadamantane)bis(pentaammineruthenium(II)) perchlorate

Chemical Property of (μ-1,3-dicyanoadamantane)bis(pentaammineruthenium(II)) perchlorate

Chemical Property:

Purity/Quality:

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Technology Process of (μ-1,3-dicyanoadamantane)bis(pentaammineruthenium(II)) perchlorate

There total 1 articles about (μ-1,3-dicyanoadamantane)bis(pentaammineruthenium(II)) perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

aquapentaammineruthenium(II) hexafluorophosphate (34843-18-0) + adamantane-1,3-dicarbonitrile (62472-38-2) → (μ-1,3-dicyanoadamantane)bis(pentaammineruthenium(II)) perchlorate (83664-85-1)

Guidance literature:

With hydrogenchloride; sodium perchlorate; lithium bromide; In acetone; in the dark under Ar, after 30 min LiBr was added to ppt. the bromide salt, which was chromd., elution with 0.3 M HCl, the the crude chloride salt was dissolved in water and reduced over Zn/Hg with Ar bubbling for 15 min, pptn. by addn. of NaClO4; the ppt. was washed with ethanol and ether, elem. anal.;

DOI:10.1021/ja00339a009

upstream raw materials:

aquapentaammineruthenium(II) hexafluorophosphate

adamantane-1,3-dicarbonitrile

Refernces