Dithiophosphoric acid O-(3-{1-[(3aR,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-2,4-dioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl}-propyl) ester S,S'-diphenyl ester

Base Information

Chemical Name:Dithiophosphoric acid O-(3-{1-[(3aR,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-2,4-dioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl}-propyl) ester S,S'-diphenyl ester
CAS No.:174193-19-2
Molecular Formula:C₄₃H₄₉N₂O₈PS₂Si
Molecular Weight:845.062
Hs Code.:

Dithiophosphoric acid O-(3-{1-[(3aR,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-2,4-dioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl}-propyl) ester S,S'-diphenyl ester

Synonyms:Dithiophosphoric acid O-(3-{1-[(3aR,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-2,4-dioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl}-propyl) ester S,S'-diphenyl ester

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Chemical Property of Dithiophosphoric acid O-(3-{1-[(3aR,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-2,4-dioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl}-propyl) ester S,S'-diphenyl ester

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Technology Process of Dithiophosphoric acid O-(3-{1-[(3aR,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-2,4-dioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl}-propyl) ester S,S'-diphenyl ester

There total 10 articles about Dithiophosphoric acid O-(3-{1-[(3aR,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-2,4-dioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl}-propyl) ester S,S'-diphenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 67941-87-1
cyclohexylammonium S,S-diphenyl phosphorodithioate

: 174193-18-1
1-[(3aR,4R,6R,6aR)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-5-(3-hydroxy-propyl)-1H-pyrimidine-2,4-dione

: 174193-19-2
Dithiophosphoric acid O-(3-{1-[(3aR,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-2,4-dioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl}-propyl) ester S,S'-diphenyl ester

Guidance literature:: With 1H-tetrazole; dapsone; In pyridine; for 1h;
DOI:10.1016/0040-4039(95)02062-4

Reference yield: 69.0%

: 23282-01-1
(S,S')-diphenylphosphorodithioate

: 174193-18-1
1-[(3aR,4R,6R,6aR)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-5-(3-hydroxy-propyl)-1H-pyrimidine-2,4-dione

: 174193-19-2
Dithiophosphoric acid O-(3-{1-[(3aR,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-2,4-dioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl}-propyl) ester S,S'-diphenyl ester

Guidance literature:: With 1H-tetrazole; dapsone;
DOI:10.1080/07328319708006125

Reference yield:

: 84500-33-4,65499-40-3
2',3',5'-tri-O-acetyl-5-iodouridine

: 174193-19-2
Dithiophosphoric acid O-(3-{1-[(3aR,4R,6R,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-2,4-dioxo-1,2,3,4-tetrahydro-pyrimidin-5-yl}-propyl) ester S,S'-diphenyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: 80 percent / Pd(PPh₃)4, CuI, triethylamine / dimethylformamide / 20 h

2: H₂ / Pd/C / ethanol / 25 h

3: 0.5 M NaOH / pyridine / 0.17 h

4: 1.) PhB(OH)2; 2.) imidazole / 1.) pyridine, 1 h; 2.) DMF, 1.5 h

5: 69 percent / 80 percent AcOH / 12 h

6: 84 percent / TMSCl / acetone / 20 h

7: 69 percent / DDS, 1H-tetrazole / pyridine / 1 h

With 1H-imidazole; 1H-tetrazole; sodium hydroxide; copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; chloro-trimethyl-silane; hydrogen; acetic acid; triethylamine; dapsone; phenylboronic acid; palladium on activated charcoal; In pyridine; ethanol; N,N-dimethyl-formamide; acetone;
DOI:10.1016/0040-4039(95)02062-4