methyl 5-O-benzyl-2,3-dideoxy-β-D-pent-2-enofuranoside

Base Information

• Chemical Name: methyl 5-O-benzyl-2,3-dideoxy-β-D-pent-2-enofuranoside
• CAS No.: 80796-99-2
• Molecular Formula: C₁₃H₁₆O₃
• Molecular Weight: 220.268
• Mol file: 80796-99-2.mol

Synonyms:methyl 5-O-benzyl-2,3-dideoxy-β-D-pent-2-enofuranoside

Chemical Property of methyl 5-O-benzyl-2,3-dideoxy-β-D-pent-2-enofuranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 5-O-benzyl-2,3-dideoxy-β-D-pent-2-enofuranoside

There total 5 articles about methyl 5-O-benzyl-2,3-dideoxy-β-D-pent-2-enofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

methyl-5-O-benzyl-3-deoxy-3-phenylselanyl-β-D-xylofuranoside → methyl 5-O-benzyl-2,3-dideoxy-β-D-pent-2-enofuranoside (80796-99-2)

Guidance literature:

With methanesulfonyl chloride; In pyridine; at 0 - 4 ℃; for 12h;

DOI:10.1021/jo5009564

Reference yield: 69.0%

methyl 5-O-benzyl-2,3-di-O-mesyl-β-D-ribofuranoside → methyl 5-O-benzyl-2,3-dideoxy-β-D-pent-2-enofuranoside (80796-99-2)

Guidance literature:

With lithium telluride; In tetrahydrofuran; 1,4-dioxane; for 20h; Heating;

DOI:10.1039/c39930000923

Reference yield:

methyl 5-benzyloxy-β-D-ribofuranoside (67737-48-8) → methyl 5-O-benzyl-2,3-dideoxy-β-D-pent-2-enofuranoside (80796-99-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 93 percent / pyridine / CH₂Cl₂ / 24 h

2: 69 percent / Et₃BHLi, Te powder / tetrahydrofuran; dioxane / 20 h / 105 °C

With pyridine; tellurium; lithium triethylborohydride; In tetrahydrofuran; 1,4-dioxane; dichloromethane;

DOI:10.1021/jo9610570

upstream raw materials:

methyl 5-benzyloxy-β-D-ribofuranoside

2,3-Anhydro-5-O-benzyl-β-D-ribofuranoside de methyle